4113-12-6

• 常用中文名：正十六烷基醚
• 常用英文名：Hexadecane,1-(hexadecyloxy)-
• CAS号：4113-12-6
• 分子式：C₃₂H₆₆O
• 分子量：466.86600
• 发布时间：2018-05-16 08:00:00
• 更新时间：2024-01-11 13:30:03

名称

• 中文名: 十六烷醚
• 英文名: Dihexadecyl Ether
• 中文别名: 十六烷基醚; 鯨蠟醚; 正十六烷基醚; 十六烷基醚
• 英文别名: Hexadecyl Ether; EINECS 223-900-7; N-HEXADECYL ETHER; 1-hexadecoxyhexadecane

物化性质

• 密度: 0.829g/cm3
• 沸点: 503.8ºC at 760mmHg
• 熔点: 55ºC
• 分子式: C₃₂H₆₆O
• 分子量: 466.86600
• 闪点: 214.1ºC
• 精确质量: 466.51100
• PSA: 9.23000
• LogP: 11.96560
• 折射率: 1.452
• 储存条件:

  避光，通风干燥处，密封保存

• 稳定性:

  常温常压下稳定

• 分子结构:

  1、摩尔折射率：152.04

  2、摩尔体积（cm³/mol）：563.1

  3、等张比容（90.2K）：1324.9

  4、表面张力（dyne/cm）：30.6

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：60.27

  7、单一同位素质量：466.511367Da

  8、标称质量：466Da

  9、平均质量：466.8658Da

MSDS

Hexadecyl Ether SAFETY DATA SHEET Section1. IDENTIFICATION Product name:Hexadecyl Ether Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified Not classified HEALTH HAZARDS ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbolsNone No signal word Signal word Hazard statementsNone None Precautionary statements: Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:Hexadecyl Ether Percent:>95.0%(GC) CAS Number:4113-12-6 Synonyms:Dihexadecyl Ether Chemical Formula:C32H66O Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Hexadecyl Ether Section5. FIRE-FIGHTING MEASURES Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Entry to non-involved personnel should be controlled around the leakage area by emergency procedures: roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it. containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with up: appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Handling is performed in a well ventilated place. Wear suitable protective equipment. Technical measures: Prevent dispersion of dust. Wash hands and face thoroughly after handling. Use a local exhaust if dust or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store in a cool and dark place. Storage conditions: Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Dust respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Solid Form:Crystal- Powder Colour:White - Very pale yellow Odour:No data available pH: No data available Melting point/freezing point:55°C Boiling point/range:No data available Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available No data available Relative density: Solubility(ies): [Water]No data available [Other solvents]No data available Section10. STABILITY AND REACTIVITY Stable under proper conditions. Chemical stability: Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hexadecyl Ether Section10. STABILITY AND REACTIVITY Hazardous decomposition Carbon monoxide, Carbon dioxide products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: No data available Fish: Crustacea:No data available No data available Algae: Persistence / degradability: No data available No data available Bioaccumulative potential(BCF): Mobility in soil Log Pow:No data available No data available Soil adsorption (Koc): Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations Not listed UN-No: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. Hexadecyl Ether SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水是不危害的，若无政府许可，勿将材料排入周围环境。

安全

• 安全声明 (欧洲): S24/25

合成路线

112-82-3 ~% 4113-12-6

文献：Zaoral Chemicke Listy, 1953 , vol. 47, p. 1872 Chem.Abstr., 1955 , p. 966

544-77-4 ~% 4113-12-6

文献：Fridau Justus Liebigs Annalen der Chemie, 1852 , vol. 83, p. 15

36653-82-4 4697-37-4 ~% 4113-12-6

文献：Plimmer; Burch Journal of the Chemical Society, 1929 , p. 298

617-86-7 628-97-7 ~% 4113-12-6

文献：Lapkin,I.I.; Povarnitsyna,T.N. J. Gen. Chem. USSR (Engl. Transl.), 1968 , vol. 38, p. 643 - 647,620 - 622

36653-82-4 544-77-4 ~% 4113-12-6

文献：Lenne,H.-U. et al. Justus Liebigs Annalen der Chemie, 1970 , vol. 732, p. 70 - 96

36653-82-4 7664-93-9 ~% 4113-12-6

文献：Senderens Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1925 , vol. 181, p. 700 Annales de Chimie (Cachan, France), 1922 , vol. <9>18, p. 123

36653-82-4 104-15-4 ~% 4113-12-6

文献：Perron; Paquot Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1949 , vol. 228, p. 584 Bulletin de la Societe Chimique de France, 1949 , p. 334

36653-82-4 ~% 4113-12-6

文献：Senderens; Aboulenc Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1930 , vol. 190, p. 151