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96-19-5生产厂家

96-19-5价格

相关CAS号：
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96-19-5

96-19-5结构式
96-19-5结构式

化源商城直购

中文名 1,2,3-三氯丙烯
英文名 1,2,3-trichloropropene
英文别名 1,2,3-Trichlor-propen
EINECS 202-487-7
1,2,3-trichloro-propen
(Z),(E)-1,2,3-trichloro-1-propene
1,2,3-Trichlor-propen-(1)
1,2,3-trichroro-1-propene
MFCD00018931
1,2,3-Trichloro-1-propene
1,2,3-trichloropropylene
Wln: G1ygu1g
1,2,3-trichloro-1-propen
Propene,1,2,3-trichloro
1,2,3-trichlor-1-propene
1,2,3-trichloro-propene
密度 1,43 g/cm3
沸点 145°C
分子式 C3H3Cl3
分子量 145.41500
闪点 82°C
精确质量 143.93000
LogP 2.54420
外观性状 液体;Colorless to Almost colorless clear liquid
折射率 1.487
储存条件

自用时以管道运输；外销可用铁桶包装。
稳定性

有毒，对人体的肺、胃有刺激作用，因产品中含少量氯丙酮，故具有催泪性。操作时应穿戴防护用具，附着在衣服上应立即更换。
　

分子结构

1、 摩尔折射率：30.39

2、 摩尔体积（cm3/mol）：105.6

3、 等张比容（90.2K）：250.2

4、 表面张力（dyne/cm）：31.4

5、 极化率（10-24cm3）：12.04
计算化学

1、 疏水参数计算参考值（XlogP）：2.2

2、 氢键供体数量：0

3、 氢键受体数量：0

4、 可旋转化学键数量：1

5、 互变异构体数量：

6、 拓扑分子极性表面积（TPSA）：0

7、 重原子数量：6

8、 表面电荷：0

9、 复杂度：57.1

10、同位素原子数量：0

11、确定原子立构中心数量：0

12、不确定原子立构中心数量：0

13、确定化学键立构中心数量：1

14、不确定化学键立构中心数量：0

15、共价键单元数量：1
更多

1. 性状：无色液体。

2. 密度（g/mL,20℃）：1.414

3. 相对蒸汽密度（g/mL,空气=1）：未确定

4. 熔点（ºC）：未确定

5. 沸点（ºC,常压）：142

6. 沸点（ºC, kPa）：未确定

7. 折射率：1.5030

8. 闪点（ºC）：未确定

9. 比旋光度（º）：未确定

10. 自燃点或引燃温度（ºC）：未确定

11. 蒸气压（mmHg,ºC）：未确定

12. 饱和蒸气压（kPa, ºC）：未确定

13. 燃烧热（KJ/mol）：未确定

14. 临界温度（ºC）：未确定

15. 临界压力（KPa）：未确定

16. 油水（辛醇/水）分配系数的对数值：未确定

17. 爆炸上限（%,V/V）：未确定

18. 爆炸下限（%,V/V）：未确定

19. 溶解性：不溶于水。溶于乙醇、氯仿。
1,2,3-Trichloropropene (cis- and trans- mixture)
SAFETY DATA SHEET
Section1. IDENTIFICATION
Product name:1,2,3-Trichloropropene (cis- and trans- mixture)
Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS
Category 4
Flammable liquids
HEALTH HAZARDS
Category 4
Acute toxicity (Oral)
Acute toxicity (Dermal)Category 3
Category 2
Acute toxicity (Inhalation)
Skin corrosion/irritationCategory 2
Category 2A
Serious eye damage/eye irritation
Specific target organ toxicityRespiratory tract irritation
- Single exposure [Category 3]
ENVIRONMENTAL HAZARDSNot classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Danger
Signal word
Hazard statementsCombustible liquid
Harmful if swallowed
Toxic in contact with skin
Fatal if inhaled
Causes skin irritation
Causes serious eye irritation
May cause respiratory irritation
Precautionary statements:
[Prevention]Keep away from flames and hot surfaces.
Do not breathe dust/fume/gas/mist/vapours/spray.
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Wear respiratory protection.
Wear protective gloves and eye/face protection.
Section2. HAZARDS IDENTIFICATION
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Immediately call a POISON CENTER or doctor/physician.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Remove/Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse.
Call a POISON CENTER or doctor/physician if you feel unwell.
[Storage]Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container through a waste management company authorized by
[Disposal]
the local government.
Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance
Substance/mixture:
Components:1,2,3-Trichloropropene (cis- and trans- mixture)
Percent:>95.0%(GC)
CAS Number:96-19-5
Chemical Formula:C3H3Cl3
Section4. FIRST AID MEASURES
Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Inhalation:
Immediately call a POISON CENTER or doctor/physician.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. Call a POISON CENTER or doctor/physician.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.
Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Unsuitable extinguishing Solid streams of water
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical:generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:
Section6. ACCIDENTAL RELEASE MEASURES
Use extra personal protective equipment (self-contained breathing apparatus). Keep
Personal precautions,
protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Section6. ACCIDENTAL RELEASE MEASURES
Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
up: material should be promptly disposed of, in accordance with appropriate laws and
regulations.
Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
hazards:case of a fire. Use spark-proof tools and explosion-proof equipment.
Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take
measures to prevent the build up of electrostatic charge. Use explosion-proof
equipment. Wash hands and face thoroughly after handling.
Use a closed system, ventilation.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place.
Store locked up.
Store away from incompatible materials such as oxidizing agents.
Comply with laws.
Packaging material:
Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
air respirator, etc. Use respirators approved under appropriate government standards
and follow local and national regulations.
Impervious gloves.
Hand protection:
Eye protection:Safety goggles. A face-shield, if the situation requires.
Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.
Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Liquid
Form:Clear
Colorless - Very pale yellow
Colour:
Odour:No data available
pH: No data available
Melting point/freezing point:No data available
Boiling point/range:145°C
Flash point:82°C
Flammability or explosive
limits:
Lower:No data available
Upper:No data available
Relative density:1.43
Solubility(ies):
[Water]No data available
[Other solvents]No data available
Section10. STABILITY AND REACTIVITY
Chemical stability:Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Open flame
Conditions to avoid:
Incompatible materials: Oxidizing agents
Section10. STABILITY AND REACTIVITY
Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride
products:
Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:ihl-rat LCLo:500 ppm/4H
orl-rat LD50:616 mg/kg
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC =No data available
NTP =No data available
Reproductive toxicity:No data available
RTECS Number:UD2450000
Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
No data available
Fish:
Crustacea:No data available
No data available
Algae:
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobility in soil
Log Pow:No data available
No data available
Soil adsorption (Koc):
Henry's LawNo data available
constant(PaM3/mol):
Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
disposing of the substance.
Section14. TRANSPORT INFORMATION
Hazards Class:6.1: Toxic substance.
2810
UN-No:
Proper shipping name:Toxic liquid, organic, n.o.s.
II
Packing group:
Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A

毒理学数据:

1、 皮肤/眼睛刺激性

开放的刺激试验：兔子，皮肤接触：10mg/24H，反应的严重程度：严重。

标准的Draize试验：兔子，眼睛接触：50mg，反应的严重程度：中度。

2、急性毒性：大鼠经口LD50：616mg/kg；大鼠经吸入LCLo：500ppm/4H；兔子经皮肤接触LD50：640μL/kg；

3、其他多剂量毒性：大鼠经吸入TCLo：36ppm/6H/4W-C；

4、 致突变性

微生物鼠伤寒沙门氏菌突变：1μmol/plate；

人HeLa细胞的DNA抑制：1700μmol/L；

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UD2450000
CHEMICAL NAME :
Propene, 1,2,3-trichloro-
CAS REGISTRY NUMBER :
96-19-5
LAST UPDATED :
199807
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C3-H3-Cl3
MOLECULAR WEIGHT :
145.41
WISWESSER LINE NOTATION :
G1YGU1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
616 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
500 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
640 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
36 ppm/6H/4W-IW-C
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Vascular - regional or general arteriolar or venous dilation Lungs, Thorax, or Respiration - dyspnea

MUTATION DATA

TYPE OF TEST :
DNA inhibition
TEST SYSTEM :
Human HeLa cell
DOSE/DURATION :
1700 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 92,427,1982

风险声明 (欧洲) 20/21/22-36/37/38
安全声明 (欧洲) S26-S36/37/39
危险品运输编码 2810
RTECS号 UD2450000
包装等级 III
危险类别 6.1(b)
海关编码 2903299090
上游产品  0

下游产品  4

其制备方法是将四氯丙烷及乙醇加到反应釜中，搅拌加热至回流，在1 h内分批加入氢氧化钾，加毕回流2 h，冷却、过滤，滤液水洗2次，水层用二氯乙烷萃取，并与油层合并，脱溶，减压蒸馏，收集74～91℃/13.3 kPa馏分即为成品。

96-19-5 preparation

海关编码 2903299090
中文概述 HS: 2903299090. 其他无环烃的不饱和氯化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素 品名, 成分含量, 用途
Summary 2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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