77628-51-4

• 常用中文名：6-甲基咪唑[2,1-B][1,3]噻唑-5-甲酸
• 常用英文名：6-Methyl-imidazo[2,1-b]thiazole-5-carboxylic acid
• CAS号：77628-51-4
• 分子式：C₇H₆N₂O₂S
• 分子量：182.20000
• 发布时间：2018-12-25 23:59:43
• 更新时间：2024-01-08 16:07:25
• 下载msds

名称

• 中文名: 6-甲基咪唑并[2,1-b][1,3]噻唑-5-甲酸
• 英文名: 6-Methylimidazo[2,1-b][1,3]thiazole-5-carboxylic acid
• 中文别名: 6-甲基咪唑[2,1-B][1,3]噻唑-5-甲酸
• 英文别名: 6-methylimidazo[2,1-b][1,3]thiazole-5-carboxylic acid

物化性质

• 密度: 1.62 g/cm3
• 熔点: 164ºC
• 分子式: C₇H₆N₂O₂S
• 分子量: 182.20000
• 精确质量: 182.01500
• PSA: 82.84000
• LogP: 1.40240
• 外观性状: 固体
• 折射率: 1.76
• 储存条件: 2-8°C，密封，干燥

MSDS

Name: 6-Methylimidazo[2 1-b][1 3]thiazole-5-carboxylic acid 97% Material Safety Data Sheet Synonym: CAS: 77628-51-4 Section 1 - Chemical Product MSDS Name:6-Methylimidazo[2 1-b][1 3]thiazole-5-carboxylic acid 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 77628-51-4 6-Methylimidazo[2,1-b][1,3]thiazole-5- 97% unlisted Hazard Symbols: XI Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 77628-51-4: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: brown Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 203 - 205 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H6N2O2S Molecular Weight: 182.2 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 77628-51-4 unlisted. LD50/LC50: Not available. Carcinogenicity: 6-Methylimidazo[2,1-b][1,3]thiazole-5-carboxylic acid - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 77628-51-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 77628-51-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 77628-51-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 符号: GHS07
• 信号词: Warning
• 危害声明: H317-H319
• 警示性声明: P280-P305 + P351 + P338
• 危害码 (欧洲): Xi: Irritant;
• 危险品运输编码: NONH for all modes of transport
• 海关编码: 2934100090

合成路线

57626-37-6 ~80% 77628-51-4

文献：Peterlin-Masic, Lucija; Malesic, Mateja; Breznik, Matej; Krbavcic, Ales Journal of Heterocyclic Chemistry, 2000 , vol. 37, # 1 p. 95 - 101

上下游产品

上游产品  1
57626-37-6
下游产品  1
83253-39-8

海关

海关编码	2934100090
中文概述	2934100090. 结构上含有一个非稠合噻唑环的化合物(不论是否氢化). 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%