10326-28-0

• 常用中文名：六水高氯酸镉
• 常用英文名：cadmium perchlorate hexahydrate
• CAS号：10326-28-0
• 分子式：CdCl₂H₁₂O₁₄
• 分子量：419.40400
• 相关类别： 无机化工 无机盐 金属卤化物及卤酸盐 金属氯化物及盐
• 发布时间：2018-05-13 08:00:00
• 更新时间：2024-01-11 10:35:15

名称

• 中文名: 六水高氯酸镉
• 英文名: cadmium perchlorate hexahydrate
• 中文别名: 高氯酸钙
• 英文别名: Cadmium Perchlorate Hexahydrate; CADMIUM PERCHLORATE 6-HYDRATE; CADMIUM PERCHLORATE,HEXAHYDRATE REAGENT; CADMIUM PERCHLORATE,99.9 (METALS BASIS); Cadmiumperchloratehexahydrate; Cadmium perchlorate hexahydrate,99.9 (metals basis); MFCD00015992

物化性质

• 密度: 2.370
• 分子式: CdCl₂H₁₂O₁₄
• 分子量: 419.40400
• 精确质量: 419.86400
• PSA: 203.92000
• LogP: 0.04030
• 外观性状: Crystals | White
• 储存条件: 室温
• 稳定性:

  65～70℃分解为四水合物。

• 水溶解性: Insoluble in water.
• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：419.863769 Da

  8、标称质量：420 Da

  9、平均质量：419.4039 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:8

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积149

  7.重原子数量:11

  8.表面电荷:0

  9.复杂度:95.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1. 性状：白色晶体

  2. 密度（g/mL,25/4℃）：2.37

  3. 相对蒸汽密度（g/mL,空气=1）：不确定

  4. 熔点（ºC）：129.4

  5. 沸点（ºC,0.67kpa或5 mmHg）：不确定

  6. 折射率：不确定

  7. 闪点（ºC）：不确定

  8. 比旋光度（ºC）：不确定

  9. 自燃点或引燃温度（ºC）不确定

  10. 蒸气压（kPa,25ºC）：不确定

  11. 饱和蒸气压（kPa,60ºC）：不确定

  12. 燃烧热（KJ/mol）：不确定

  13. 临界温度（ºC）：50.3

  14. 临界压力（KPa）：不确定

  15. 油水（辛醇/水）分配系数的对数值：不确定

  16. 爆炸上限（%,V/V）：不确定

  17. 爆炸下限（%,V/V）：不确定

  18. 溶解性：溶于水。

MSDS

Section 1: Product Identification Chemical Name:Cadmium perchlorate hexahydrate, 99% CAS Registry Number:10326-28-0 Formula:Cd(ClO4)2.6H2O EINECS Number:none Chemical Family:metal perchlorate salt Synonym:Perchloric acid, Cadmium(II) salt, hexahydrate Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound10326-28-0100%0.002mg/m30.005mg/m3 Section 3: Hazards Identification Oral toxicity and inhalation toxicity is high. Damage to liver and kidney function may result. May cause cancer. Emergency Overview: Primary Routes of Exposure:Ingestion Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation of dust and fumes can lead a cough, headache, shortness of breath, chest pains, and pulmonary Inhalation: edema. Ingestion:Ingestion may lead to sudden nausea, vomiting, bloody diarrhea, weakness, and convulsions. Acute Health Affects:Toxic by inhalation and if swallowed. May be irritating. Loss of sense of smell, weight loss, liver and kidney damage. Cadmium is a recognized carcinogen of the Chronic Health Affects:connective tissue, lungs and the liver. Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected. NTP:Yes IARC:Yes OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:Water spray Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters Special Fire Fighting Procedures: should be equipped with a NIOSH approved self-contained breathing apparatus. Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen chloride fumes. Decomposion Products: Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with Unusual Fire or Explosion Hazards: combustibles. SECTION 6: Accidental Release Measures Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute Spill and Leak Procedures: with water. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white xtl. Molecular Weight:311.30 (419.39) Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:very soluble SECTION 10: Stability and Reactivity Stability:Air and moisture stable solid Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Any contact with combustible matter. Incompatibility:Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids Decomposition Products:Oxygen, Cadmium oxide, hydrogen chloride, SECTION 11: Toxicological Information RTECS Data:No specific information available on this product. Carcinogenic Effects:Carcinogen (as Ca) Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No data available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Oxidizing solid, Toxic, N.O.S. Hazard Class (CFR):5.1 Additional Hazard Class (CFR):6.1 Packaging Group (CFR):II UN ID Number (CFR):UN# 3087 Shipping Name (IATA):Oxidizing Solid, Toxic, N.O.S. Hazard Class (IATA):5.1 Additional Hazard Class (IATA):6.1 Packaging Group (IATA):II UN ID Number (IATA):UN# 3087 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See Category Code N078 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): O;Xn;N
• 风险声明 (欧洲): 8-36/37/38
• 安全声明 (欧洲): 17-26-36/37/39
• 危险品运输编码: UN 1481
• 包装等级: II
• 危险类别: 5.1

制备

将碳酸镉与高氯酸水溶液反应、蒸发浓缩得到晶体。