14181-72-7

• 常用中文名：2-溴-1-苯乙酮肟
• 常用英文名：2-bromo-1-phenyl-1-ethanone oxime
• CAS号：14181-72-7
• 分子式：C₈H₈BrNO
• 分子量：214.05900
• 发布时间：2018-02-10 08:00:00
• 更新时间：2024-01-02 12:10:26

名称

• 中文名: 2-溴-1-苯乙酮肟
• 英文名: 2-bromo-1-phenyl-1-ethanone oxime
• 英文别名: phenacyl bromide oxime; 2-Brom-1-phenyl-aethanon-oxim; 2-bromo-1-phenyl-ethanone oxime; bromoacetophenone oxime

物化性质

• 密度: 1.45g/cm3
• 沸点: 296.8ºC at 760mmHg
• 熔点: 97-100ºC
• 分子式: C₈H₈BrNO
• 分子量: 214.05900
• 闪点: 133.3ºC
• 精确质量: 212.97900
• PSA: 32.59000
• LogP: 2.25980
• 蒸汽压: 0.00063mmHg at 25°C
• 折射率: 1.57

MSDS

Name: 2-Bromo-1-phenyl-1-ethanone oxime 97% Material Safety Data Sheet Synonym: CAS: 14181-72-7 Section 1 - Chemical Product MSDS Name:2-Bromo-1-phenyl-1-ethanone oxime 97% Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 14181-72-7 2-Bromo-1-phenyl-1-ethanone oxime 97% unlisted Hazard Symbols: C Risk Phrases: 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 14181-72-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 97 - 100 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H8BrNO Molecular Weight: 214.06 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 14181-72-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Bromo-1-phenyl-1-ethanone oxime - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE SOLID, N.O.S.* Hazard Class: 8 UN Number: 1759 Packing Group: III IMO Shipping Name: CORROSIVE SOLID, N.O.S. Hazard Class: 8 UN Number: 1759 Packing Group: III RID/ADR Shipping Name: CORROSIVE SOLID, N.O.S. Hazard Class: 8 UN Number: 1759 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 14181-72-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 14181-72-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 14181-72-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): C: Corrosive;
• 风险声明 (欧洲): R34
• 海关编码: 2928000090

合成路线

70-11-1 ~% 14181-72-7

文献：Yang, Hai-tao; Ruan, Xiao-Jiao; Miao, Chun-bao; Xi, Hai-tao; Jiang, Yan; Meng, Qi; Sun, Xiao-qiang Tetrahedron Letters, 2009 , vol. 50, # 52 p. 7337 - 7339

2142-69-0 ~% 14181-72-7

文献：Rad, Mohammad Navid Soltani; Khalafi-Nezhad, Ali; Behrouz, Somayeh Helvetica Chimica Acta, 2009 , vol. 92, # 9 p. 1760 - 1774

546-88-3 70-11-1 ~% 14181-72-7

文献：Madabhushi, Sridhar; Vangipuram, Venkata Sairam; Mallu, Kishore Kumar Reddy; Chinthala, Narsaiah; Beeram, China Ramanaiah Advanced Synthesis and Catalysis, 2012 , vol. 354, # 8 p. 1413 - 1416

98-86-2 ~% 14181-72-7

文献：Katoh, Akira; Yamaguchi, Mika; Saito, Ryota; Adachi, Yusuke; Sakurai, Hiromu Chemistry Letters, 2004 , vol. 33, # 10 art. no. CL-040767, p. 1274 - 1275

上下游产品

上游产品  4
70-11-1 2142-69-0 546-88-3 98-86-2
下游产品  10
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海关

海关编码	2928000090
中文概述	2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%