6105-75-5

• 常用中文名：2-甲基-1-吗啉基-2-丙胺
• 常用英文名：1,1-Dimethyl-2-morpholin-4-yl-ethylamine
• CAS号：6105-75-5
• 分子式：C₈H₁₈N₂O
• 分子量：158.24100
• 发布时间：2018-08-26 19:38:11
• 更新时间：2024-01-02 10:01:26

名称

• 中文名: 2-甲基-1-吗啉基-2-丙胺
• 英文名: 2-Methyl-1-morpholinopropan-2-amine
• 中文别名: 2-甲基-1-吗啉-2-丙胺; 1,1-二甲基-2-吗啉-4-乙胺
• 英文别名: 1,1-Dimethyl-2-morpholin-4-yl-ethylamine

物化性质

• 密度: 0.971 g/cm3
• 沸点: 227.6ºC at 760 mmHg
• 分子式: C₈H₁₈N₂O
• 分子量: 158.24100
• 闪点: 91.4ºC
• 精确质量: 158.14200
• PSA: 38.49000
• LogP: 0.69410
• 折射率: 1.473

MSDS

Name: 2-Methyl-1-morpholino-2-propanamine Material Safety Data Sheet Synonym: None Known CAS: 6105-75-5 Section 1 - Chemical Product MSDS Name:2-Methyl-1-morpholino-2-propanamine Material Safety Data Sheet Synonym:None Known Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 6105-75-5 2-Methyl-1-morpholino-2-propanamine 97+ unlisted Hazard Symbols: C Risk Phrases: 35 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Causes severe burns. Potential Health Effects Eye: Causes severe eye burns. Skin: Causes severe burns. Ingestion: Causes severe digestive tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Chronic exposure may cause effects similar to those of acute exposure. Section 4 - FIRST AID MEASURES Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes). Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Discard contaminated shoes. Use only with adequate ventilation. Storage: Store in a tightly closed container. Corrosives area. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 6105-75-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H18N2O Molecular Weight: 158.24 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: None reported. Incompatibilities with Other Materials: Oxidizing agents, acids, acid chlorides. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 6105-75-5: QD7400000 LD50/LC50: Not available. Carcinogenicity: 2-Methyl-1-morpholino-2-propanamine - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Ecotoxicity: Fish: Pseudomonas putida: Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing Group: II IMO Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing Group: II RID/ADR Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S. Hazard Class: 8 UN Number: 2735 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 35 Causes severe burns. Safety Phrases: S 6 Keep under nitrogen. S 23 Do not inhale gas/fumes/vapour/spray. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 6105-75-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 6105-75-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 6105-75-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

CHEMICAL IDENTIFICATION RTECS NUMBER : QD7400000 CHEMICAL NAME : Morpholine, 4-(2-amino-2-methylpropyl)- CAS REGISTRY NUMBER : 6105-75-5 BEILSTEIN REFERENCE NO. : 0106002 LAST UPDATED : 199612 DATA ITEMS CITED : 1 MOLECULAR FORMULA : C8-H18-N2-O MOLECULAR WEIGHT : 158.28 WISWESSER LINE NOTATION : T6N DOTJ A1XZ1&1 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 178 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00070

安全

• 危害码 (欧洲): C: Corrosive;
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): S23-S26-S36/37/39-S45
• 海关编码: 2934999090

合成路线

33453-98-4 ~% 6105-75-5

文献：Journal of the American Chemical Society, , vol. 72, p. 2978

110-91-8 2658-24-4 ~% 6105-75-5

文献：Journal of the American Chemical Society, , vol. 70, p. 184

上下游产品

上游产品  3
33453-98-4 110-91-8 2658-24-4
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海关

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%