15002-31-0

• 常用中文名：六氰基尿酸钾(II)水合物
• 常用英文名：potassium hexacyanoruthenate(ii) hydrate
• CAS号：15002-31-0
• 分子式：C₆H₂K₄N₆ORu+
• 分子量：431.58300
• 发布时间：2018-03-29 08:00:00
• 更新时间：2024-01-10 15:11:28

名称

• 中文名: 六氰基钌(II)酸钾水合物
• 英文名: potassium hexacyanoruthenate(ii) hydrate
• 中文别名: 氰基金属钾盐
• 英文别名: Potassium Hexacyanoruthenate Trihydrate; MFCD00168064; EINECS 239-097-1; Cyanometalpotassiumsalt; potassium ruthenium cyanide

物化性质

• 沸点: 25.7ºC at 760mmHg
• 分子式: C₆H₂K₄N₆ORu+
• 分子量: 431.58300
• 精确质量: 431.78800
• PSA: 151.97000
• LogP: 0.03638
• 蒸汽压: 740mmHg at 25°C
• 储存条件:

  常温密闭避光，通风干燥

• 稳定性:

  常温常压下稳定

  避免的物料： 氧化物 酸 光

• 计算化学:

  1、疏水参数计算参考值（XlogP）：

  2、氢键供体数量：0

  3、氢键受体数量：12

  4、旋转化学键数量；0

  5、互变异构体数量：

  6、拓扑分子极性表面积（TPSA）；143

  7、重原子数量：17

  8、表面电荷：0

  9、复杂度：10

  10、同位素原子数量：0

  11、确定原子立构中心数量：0

  12、不确定原子立构中心数量：0

  13、确定化学键立构中心数量：0

  14、不确定化学键立构中心数量：0

  15、共价键单元数量：11

• 更多:

  1.性状：未确定

  2.密度（g/mL,25/4℃）：未确定

  3.相对蒸汽密度（g/mL,空气=1）：未确定

  4.熔点（ºC）：未确定

  5.沸点（ºC,常压）：未确定

  6.沸点（ºC,5.2kPa）：未确定

  7.折射率：未确定

  8.闪点（ºC）：未确定

  9.比旋光度（º）：未确定

  10.自燃点或引燃温度（ºC）：未确定

  11.蒸气压（kPa,25ºC）：未确定

  12.饱和蒸气压（kPa,60ºC）：未确定

  13.燃烧热（KJ/mol）：未确定

  14.临界温度（ºC）：未确定

  15.临界压力（KPa）：未确定

  16.油水（辛醇/水）分配系数的对数值：未确定

  17.爆炸上限（%,V/V）：未确定

  18.爆炸下限（%,V/V）：未确定

  19.溶解性：未确定

MSDS

Section 1: Product Identification Chemical Name:Potassium hexacyanoruthenate (II) hydrate CAS Registry Number:15002-31-0 Formula:K4Ru(CN)6.XH2O EINECS Number:239-097-1 Chemical Family:metal cyano complex Synonym:Potassium ruthenocyanide, Ruthenate(4-), hexakis(cyano-C)-, tetrapotassium Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound15002-31-0100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to skin, eyes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, and vomiting. Acute Health Affects:Irritating to skin, eyes and respiratory tract. The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards Chronic Health Affects: may be present. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:none required If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self- contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable Spill and Leak Procedures: inert material and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry area away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white powder Molecular Weight:413.59 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Very strong oxidizing agents such as nitric acid may produce toxic volatile ruthenium tetroxide. Incompatibility:Mineral acids, oxidizing agents and active metals Decomposition Products:carbon dioxide, carbon monoxide, nitrogen oxides, organic fumes, and ruthenium oxide SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 通常对水体是稍微有害的，不要将未稀释或大量产品接触地下水，水道或污水系统，未经政府许可勿将材料排入周围环境。

安全

• 危害码 (欧洲): T: Toxic;
• 风险声明 (欧洲): 23/24/25-36/37/38
• 安全声明 (欧洲): 26-36/37/39-45
• 危险品运输编码: UN 1588 6.1/PG 2
• 包装等级: III
• 危险类别: 6.1(b)