14101-95-2

• 常用中文名：三-I-丙基氯化锡
• 常用英文名：chloro-tri(propan-2-yl)stannane
• CAS号：14101-95-2
• 分子式：C₉H₂₁ClSn
• 分子量：283.41700
• 发布时间：2018-08-13 13:17:22
• 更新时间：2024-01-09 11:45:18

名称

• 中文名: 三-I-丙基氯化锡
• 英文名: chloro-tri(propan-2-yl)stannane
• 中文别名: 三异丙基氯化锡
• 英文别名: Triisopropyltin chloride; Chlorotriisopropylstannane; Triisopropylzinnchlorid; Triisopropylchlorostannane; Stannane,chlorotriisopropyl; Tri-i-propylzinnchlorid

物化性质

• 沸点: 219.8ºC at 760mmHg
• 分子式: C₉H₂₁ClSn
• 分子量: 283.41700
• 闪点: 86.7ºC
• 精确质量: 284.03500
• LogP: 4.40070
• 蒸汽压: 0.173mmHg at 25°C
• 储存条件:

  密闭于阴凉干燥环境中

• 稳定性:

  遵照规定使用和储存则不会分解。

• 分子结构:

  1、摩尔折射率：无可用

  2、 摩尔体积（cm³/mol）：无可用

  3、 等张比容（90.2K）：无可用

  4、 表面张力（dyne/cm）：无可用

  5、 极化率：无可用

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:3

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:11

  8.表面电荷:0

  9.复杂度:97

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无可用

  2. 密度（g/mL,25/4℃）：无可用

  3. 相对蒸汽密度（g/mL,空气=1）：无可用

  4. 熔点（ºC）：无可用

  5. 沸点（ºC,常压）：无可用

  6. 沸点（ºC,5.2kPa）：无可用

  7. 折射率：无可用

  8. 闪点（ºC）：无可用

  9. 比旋光度（º）：无可用

  10. 自燃点或引燃温度（ºC）：无可用

  11. 蒸气压（kPa,25ºC）：无可用

  12. 饱和蒸气压（kPa,60ºC）：无可用

  13. 燃烧热（KJ/mol）：无可用

  14. 临界温度（ºC）：无可用

  15. 临界压力（KPa）：无可用

  16. 油水（辛醇/水）分配系数的对数值：无可用

  17. 爆炸上限（%,V/V）：无可用

  18. 爆炸下限（%,V/V）：无可用

  19. 溶解性：无可用

MSDS

Section 1: Product Identification Chemical Name:Tri-i-propyltin chloride, min. 98% CAS Registry Number:14101-95-2 Formula:(C3H7)3SnCl EINECS Number:none Chemical Family:organotin compound Synonym:Chlorotriisopropylstannane, Chlorotriisopropyltin Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound14101-95-2100%0.1mg/m3 (Sn-org)0.1mg/m3 (Sn-org) Section 3: Hazards Identification Emergency Overview:Toxic if swallowed. Severe irritant by inhalation and in contact with skin. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:May cause severe irritation to the eyes. Skin Contact:May causes severe irritation of the skin. Forms hydrogen chloride upon exposure to the atmosphere. Inhalation may lead to irritation of the respiratory Inhalation: tract. Ingestion:Toxic if swallowed. Toxic by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory tract. Acute Health Affects: May cause eye and skin burns, dyspnea (breathing difficulty) and pulmonary edema. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit hydrochloric acid fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Store material in a tightly sealed container away from moisture. If possible, handle material in an efficient fume Handling and Storage: hood. Prolonged exposure to the atmosphere will lead to degradation of the product. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:colorless liquid Molecular Weight:283.43 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents and halogens Decomposition Products:carbon monoxide, carbon dioxide, hydrochloric acid, organic fumes, and tin oxychlorides. SECTION 11: Toxicological Information RTECS Data:Oral(rat); LD50: 44mg/kg. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. SECTION 13: Disposal Considerations Disposal:Avoid release to the environment. Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Organotin compounds, Liquid, N.O.S. Hazard Class (CFR):6.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 2788 Shipping Name (IATA):Organotin compound, Liquid, N.O.S. Hazard Class (IATA):6.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 2788 SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 试验方法：口服 摄入剂量： 44毫克/千克 测试对象：啮齿动物-鼠 毒性类型：急性 毒性作用： 详细的毒副作用没有报告以外的其他致死剂量值 生态学数据: 该物质对环境可能有危害，对水体应给予特别注意。 CHEMICAL IDENTIFICATION RTECS NUMBER : WH6848000 CHEMICAL NAME : Stannane, chlorotriisopropyl- CAS REGISTRY NUMBER : 14101-95-2 LAST UPDATED : 198910 DATA ITEMS CITED : 1 MOLECULAR FORMULA : C9-H21-Cl-Sn MOLECULAR WEIGHT : 283.44 HEALTH HAZARD DATA ACUTE TOXICITY DATA TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 44 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : PHARAT Pharmazie. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1946- Volume(issue)/page/year: 37,801,1982

安全

• 海关编码: 2931900090

合成路线

2949-42-0 ~% 38802-82-3 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93

596-43-0 2949-42-0 ~0% 187737-37-7 519-73-3 详细

文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93

950-11-8 ~% 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272

19464-54-1 ~% 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272

19411-59-7 ~% 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272

2949-42-0 ~% 30615-19-1 14101-95-2

文献：Abraham, M. H.; Grellier, P. L. J. Chem. Soc. Perkin Trans. II, 1973 , p. 1132 - 1137

2949-42-0 ~% 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93

2949-42-0 ~% 67-66-3 13275-19-9 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.4.3, page 92 - 93

753-73-1 19411-59-7 ~% 1066-45-1 14101-95-2

文献：Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.4, page 270 - 272

上下游产品

上游产品  4
2949-42-0 596-43-0 19411-59-7 753-73-1
下游产品  1
759-23-9

海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%