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25658-42-8生产厂家

25658-42-8价格

25658-42-8

25658-42-8结构式
25658-42-8结构式

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中文名 氮化锆
英文名 azanylidynezirconium
英文别名 Zirconium nitride
MFCD00049642
EINECS 247-166-2
nitridozirconium
密度 7.09
熔点 2980ºC
分子式 NZr
分子量 105.23100
精确质量 103.90800
PSA 23.79000
LogP 0.01508
外观性状 棕色粉末
储存条件

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方。呈超导性。
稳定性

如果遵照规格使用和储存则不会分解

避免接触氧化物
计算化学

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积23.8

7.重原子数量:2

8.表面电荷:0

9.复杂度:10

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

更多

1. 性状:淡黄色立方结晶,属氯化钠型结构。

2. 密度(g/mL,25/4℃):7.09

3. 相对蒸汽密度(g/mL,空气=1):未确定

4. 熔点(ºC):2960

5. 沸点(ºC,常压):未确定

6. 沸点(ºC,5.2kPa):未确定

7. 折射率:未确定

8. 闪点(ºC):未确定

9. 比旋光度(º):未确定

10. 自燃点或引燃温度(ºC):未确定

11. 蒸气压(kpa,20ºC):未确定

12. 饱和蒸气压(kPa,60ºC):未确定

13. 燃烧热(KJ/mol):未确定

14. 临界温度(ºC):未确定

15. 临界压力(KPa):未确定

16. 油水(辛醇/水)分配系数的对数值:未确定

17. 爆炸上限(%,V/V):未确定

18. 爆炸下限(%,V/V):未确定

19. 溶解性:溶于浓氢氟酸、浓硫酸及热碱中,微溶于稀盐酸和稀硫酸。在空气中加热至700℃以上即氧化成氧化锆。


Section 1: Product Identification
Chemical Name:Zirconium nitride, 98%
CAS Registry Number:25658-42-8
Formula:ZrN
EINECS Number:247-166-2
Chemical Family:metal nitride
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound25658-42-8100%5mg/m3 (as Zr)5mg/m3 (as Zr)

Section 3: Hazards Identification
Emergency Overview:May be irritating to skin, eyes and mucous membranes.
Primary Routes of Exposure:Ingestion
Eye Contact:May cause mild to moderate irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:Dust may be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information is available on the physiological effects of ingestion.
May be irritating to skin, eyes and respiratory tract. May slowly form ammonia, a choking gas, in contact with
Acute Health Affects:
moisture.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus.
Hazardous Combustion andIf involved in a fire this material may release toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:May evolve ammonia gas if moist. Sweep up the solids and dispose of properly.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a sealed container. Keep away from heat.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:brown powder
Molecular Weight:105.23
Melting Point:2980°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:7.09
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:No hazardous polymerization.
Conditions to Avoid:water and aqueous acids
Incompatibility:water and acids
Decomposition Products:zirconium oxide and ammonia

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

生态学数据:

通常来说对水是不危害的,若无政府许可,勿将材料排入周围环境

个人防护装备 Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
危险品运输编码 UN3178
WGK德国 3
包装等级 III
危险类别 4.1

1.将金属锆与氮气在1100~1200℃的温度下进行直接氮化。

2.采用四氯化锆法。以四氯化锆和氨为原料制备氮化锆,反应式如下。

25658-42-8 preparation

四氯化锆首先与氨形成加成物,再加热至750℃,转化成四氮化三锆(Zr3N4),进一步加热至1200℃转化成氮化锆(ZrN)。也可由四氯化锆和氨在氢气存在下,于1000℃以上反应制得氮化锆。