433337-23-6

• 常用中文名：1-癸基-3-甲基咪唑双三氟甲磺酰亚胺盐
• 常用英文名：1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imid
• CAS号：433337-23-6
• 分子式：C₁₆H₂₇F₆N₃O₄S₂
• 分子量：503.524
• 发布时间：2018-12-26 13:53:03
• 更新时间：2024-01-14 10:52:48

名称

• 中文名: 1-癸基-3-甲基咪唑双(三氟甲烷磺酰)亚胺盐
• 英文名: 1-Decyl-3-Methylimidazolium Bis(Trifluoromethylsulfonyl)Imide
• 中文别名: 1-癸基-3-甲基咪唑双三氟甲磺酰亚胺盐; 1-癸基-3-甲基咪唑二(三氟甲烷磺酰基)酰亚胺
• 英文别名: 1-Decyl-3-methyl-1H-imidazol-3-ium bis[(trifluoromethyl)sulfonyl]azanide; 1-Decyl-3-methyl-1H-imidazol-3-ium bis[(trifluoromethyl)sulfonyl] azanide; 1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide; 1-decyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide

物化性质

• 熔点: -19 °C
• 分子式: C₁₆H₂₇F₆N₃O₄S₂
• 分子量: 503.524
• 精确质量: 503.134705
• PSA: 93.85000
• LogP: 6.67420
• 外观性状: 液体;Colorless to Light orange to Yellow clear liquid
• 折射率: 1.44
• 储存条件: 室温，干燥

MSDS

1-Decyl-3-methylimidazolium Revision number: 5 Bis(trifluoromethanesulfonyl)imide SAFETY DATA SHEET Section1. IDENTIFICATION Product name:1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDSNot classified Not classified HEALTH HAZARDS ENVIRONMENTAL HAZARDSNot classified GHS label elements, including precautionary statements Pictograms or hazard symbolsNone Signal wordNo signal word Hazard statementsNone Precautionary statements:None Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Substance/mixture: Components:1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide >98.0%(LC)(T) Percent: CAS Number:433337-23-6 Chemical Formula:C16H27F6N3O4S2 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Remove/Take off immediately all contaminated clothing. Rinse skin with Skin contact: water/shower. If skin irritation or rash occurs: Get medical advice/attention. Rinse cautiously with water for several minutes. Remove contact lenses, if present Eye contact: and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth. Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Suitable extinguishingDry chemical, foam, water spray, carbon dioxide. media: Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. 1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide Section5. FIRE-FIGHTING MEASURES Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapour or mist. Wash hands and face thoroughly after handling. Use a ventilation, local exhaust if vapour or aerosol will be generated. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool and dark place. Store away from incompatible materials such as oxidizing agents. Packaging material:Comply with laws. Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Install a closed system or local exhaust as possible so that workers should not be Engineering controls: exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Hand protection:Protective gloves. Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Form:Clear Colour:Pale yellow - Yellow Odour:No data available pH: No data available Melting point/freezing point:-19°C No data available Boiling point/range: Flash point:No data available Flammability or explosive limits: No data available Lower: Upper:No data available 1.29 Relative density: Solubility(ies): No data available [Water] [Other solvents]No data available Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. 1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide Section10. STABILITY AND REACTIVITY Possibility of hazardous No special reactivity has been reported. reactions: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Hydrogen fluoride, Sulfur products:oxides Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: IARC =No data available No data available NTP = Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil No data available Log Pow: Soil adsorption (Koc):No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations Not listed UN-No: Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. 1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide SECTION 16 - ADDITIONAL INFORMATION N/A

合成路线

616-47-7 112-29-8 90076-65-6 ~% 433337-23-6

文献：Dzyuba, Sergei V.; Bartsch, Richard A. Tetrahedron Letters, 2002 , vol. 43, # 26 p. 4657 - 4659

112-29-8 ~% 433337-23-6

文献：Alammar, Tarek; Mudring, Anja-Verena ChemSusChem, 2011 , vol. 4, # 12 p. 1796 - 1804

654077-64-2 91742-21-1 ~% 433337-23-6

文献：Murray, Samuel M.; O'Brien, Richard A.; Mattson, Kaila M.; Ceccarelli, Christopher; Sykora, Richard E.; West, Kevin N.; Davis Jr., James H. Angewandte Chemie - International Edition, 2010 , vol. 49, # 15 p. 2755 - 2758

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