中文名 | 6-氯-2-甲基-3,4-二氢-2H-1-苯并噻因-4-酮 |
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英文名 | 6-chloro-2-methyl-2,3-dihydrothiochromen-4-one |
英文别名 |
6-chloro-2-methyl-3,4-dihydro-2H-1-benzothiin-4-one
4H-1-Benzothiopyran-4-one,6-chloro-2,3-dihydro-2-methyl HMS1668K16 6-chloro-2-methylthiochroman-4-one 6-chloro-2-methyl-1-thiochroman-4-one |
密度 | 1.295g/cm3 |
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沸点 | 343ºC at 760mmHg |
熔点 | 64ºC |
分子式 | C10H9ClOS |
分子量 | 212.69600 |
闪点 | 161.2ºC |
精确质量 | 212.00600 |
PSA | 42.37000 |
LogP | 3.40700 |
蒸汽压 | 7.24E-05mmHg at 25°C |
折射率 | 1.602 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 147713-35-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 64 - 65 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H9ClOS Molecular Weight: 212.7 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, carbon monoxide, oxides of sulfur, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 147713-35-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 6-Chloro-2-methyl-3,4-dihydro-2H-1-benzothiin-4-one - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 147713-35-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 147713-35-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 147713-35-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
~% 147713-35-7 |
文献:FUJIFILM Corporation; SAKITA, Kyouhei; KIKUCHI, Wataru; YUMOTO, Masatoshi; HIKITA, Masanori Patent: US2013/171415 A1, 2013 ; Location in patent: Paragraph 0472 ; |
~92% 147713-35-7 |
文献:Clayton, Stephen E.; Gabbutt, Christopher D.; Hepworth, John D.; Mark Heron Tetrahedron, 1993 , vol. 49, # 4 p. 939 - 946 |
~% 147713-35-7 |
文献:Clayton, Stephen E.; Gabbutt, Christopher D.; Hepworth, John D.; Mark Heron Tetrahedron, 1993 , vol. 49, # 4 p. 939 - 946 |
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