4543-47-9

• 常用中文名：3-呋喃基甲胺
• 常用英文名：1-(3-Furyl)methanamine
• CAS号：4543-47-9
• 分子式：C₅H₇NO
• 分子量：97.115
• 发布时间：2018-07-09 15:52:18
• 更新时间：2024-01-02 19:00:35
• 下载msds

名称

• 中文名: 3-呋喃基甲胺
• 英文名: furan-3-ylmethanamine
• 中文别名: 3-(氨甲基)呋喃
• 英文别名: 3-Furanmethanamine; Furan-3-Yl-Methanamine; 3-aminomethylfurane; Furan-3-ylmethanamine; (fur-3-ylmethyl)amine; 3-furylmethyl amine; 3-(aminomethyl)furan; furan-3-ylmethylamine; 1-(3-Furyl)methanamine

物化性质

• 密度: 1.1±0.1 g/cm3
• 沸点: 136.4±15.0 °C at 760 mmHg
• 分子式: C₅H₇NO
• 分子量: 97.115
• 闪点: 36.3±20.4 °C
• 精确质量: 97.052765
• PSA: 39.16000
• LogP: 0.25
• 蒸汽压: 7.4±0.3 mmHg at 25°C
• 折射率: 1.497
• 储存条件: 室温

MSDS

Name: 3-Furylmethylamine tech Material Safety Data Sheet Synonym: 3-Aminomethylfura CAS: 4543-47-9 Section 1 - Chemical Product MSDS Name:3-Furylmethylamine tech Material Safety Data Sheet Synonym:3-Aminomethylfura Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 4543-47-9 3-Furylmethylamine unlisted Hazard Symbols: C Risk Phrases: 20/21/22 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Causes burns.Air sensitive. Potential Health Effects Eye: Causes eye burns. Skin: Harmful if absorbed through the skin. Causes skin burns. Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns. Inhalation: Harmful if inhaled. Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area. Store under an inert atmosphere. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 4543-47-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: amine-like pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 52 - 54 deg C @15mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C5H7NO Molecular Weight: 97 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to air. Incompatibilities with Other Materials: Oxidizing agents, air. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 4543-47-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-Furylmethylamine - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S.* Hazard Class: 8 (6.1) UN Number: 2922 Packing Group: III IMO Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S. Hazard Class: 8 (6.1) UN Number: 2922 Packing Group: III RID/ADR Shipping Name: CORROSIVE LIQUID, TOXIC, N.O.S. Hazard Class: 8 (6.1) UN Number: 2922 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 34 Causes burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 4543-47-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 4543-47-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 4543-47-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 风险声明 (欧洲): R10
• 安全声明 (欧洲): 26-36/37/39
• 危险品运输编码: UN 2733
• 海关编码: 2932190090

合成路线

4412-91-3 ~% 4543-47-9

文献：Katsura, Yousuke; Nishino, Shigetaka; Ohno, Mitsuko; Sakane, Kazuo; Matsumoto, Yoshimi; Morinaga, Chizu; Ishikawa, Hirohumi; Takasugi, Hisashi Journal of Medicinal Chemistry, 1999 , vol. 42, # 15 p. 2920 - 2926

609-35-8 ~% 4543-47-9

文献：The Dow Chemical Company Patent: US5505931 A1, 1996 ;

30078-65-0 ~99% 4543-47-9

文献：Enthaler, Stephan; Addis, Daniele; Junge, Kathrin; Erre, Giulia; Beller, Matthias Chemistry - A European Journal, 2008 , vol. 14, # 31 p. 9491 - 9494

131052-42-1 ~% 4543-47-9

文献：Katsura, Yousuke; Nishino, Shigetaka; Ohno, Mitsuko; Sakane, Kazuo; Matsumoto, Yoshimi; Morinaga, Chizu; Ishikawa, Hirohumi; Takasugi, Hisashi Journal of Medicinal Chemistry, 1999 , vol. 42, # 15 p. 2920 - 2926

498-60-2 ~% 4543-47-9

文献：Lopez-Rodriguez, Maria L.; Viso, Alma; Ortega-Gutierrez, Silvia; Fowler, Christopher J.; Tiger, Gunnar; De Lago, Eva; Fernandez-Ruiz, Javier; Ramos, Jose A. Journal of Medicinal Chemistry, 2003 , vol. 46, # 8 p. 1512 - 1522

上下游产品

上游产品  5
4412-91-3 609-35-8 30078-65-0 131052-42-1
498-60-2
下游产品  1
390824-20-1

海关

海关编码	2932190090
中文概述	2932190090 其他结构上有非稠合呋喃环化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%