58356-65-3

• 常用中文名：锰(III)内四苯基卟啉乙酸酯
• 常用英文名：manganese(iii) acetate meso-tetraphenylporphine
• CAS号：58356-65-3
• 分子式：C₄₆H₃₂MnN₄O₂
• 分子量：727.71000
• 相关类别： 有机原料 羧酸类化合物及衍生物 羧酸酯及其衍生物的盐
• 发布时间：2018-02-14 08:00:00
• 更新时间：2024-01-11 17:02:19

• 化学试剂

名称

• 中文名: 间四苯基卟吩乙酸锰(III)
• 英文名: acetic acid,manganese(2+),5,10,15,20-tetraphenylporphyrin-22,24-diide
• 中文别名: 间四苯基卟吩乙酸锰
• 英文别名: 2,7,12,17-tetraphenyl-21,23,24,25-tetraaza-22-manganahexacyclo[9.9.3.1^{3,6}.1^{13,16}.0^{8,23}.0^{18,21}]pentacosa-1,3(25),4,6,8,10,12,14,16(24),17,19-undecaene; MFCD00216548; Mn(TPP)(OAc); Mn(meso-tetraphenylporphyrin)OAc; manganese(III)(meso-tetraphenylporphyrin)OAc; MANGANESE meso-TETRAPHENYLPORPHINE ACETATE; acetato[5,10,15,20-tetra(phenyl)porphyrinato]manganese(III)

物化性质

• 分子式: C₄₆H₃₂MnN₄O₂
• 分子量: 727.71000
• 精确质量: 727.19100
• PSA: 71.88000
• LogP: 6.52870
• 外观性状: Powder | greenish black
• 储存条件:

  在密封的贮藏器内，并放置阴凉，干燥的地方避光保存

• 稳定性:

  避免接触氧化物

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:1

  3.氢键受体数量:6

  4.可旋转化学键数量:4

  5.互变异构体数量:无

  6.拓扑分子极性表面积64

  7.重原子数量:53

  8.表面电荷:0

  9.复杂度:1370

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1. 性状：深绿色粉末

  2. 密度（g/cm³ 25/4℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC 6mmHg）：未确定

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（℉）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值（25℃）：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性(mg/mL)：水：未确定

MSDS

Section 1: Product Identification Chemical Name:Manganese (III) meso-tetraphenylporphine acetate CAS Registry Number:58356-65-3 Formula:Mn(C44H28N4)OOCCH3 EINECS Number:none Chemical Family:metal porphine (porphyrin) complex Synonym:Manganic (III) meso-tetraphenylporphine acetate Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound58356-65-3100%0.2mg/m3 (as Mn)5mg/m3 (as Mn - Section 3: Hazards Identification Emergency Overview:May be irritating to eyes, skin and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Inhalation, ingestion. Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Dust may be irritating to the nose, mucous membranes and respiratory tract and cause chronic health Inhalation: problems. Ingestion:No information available on the physiological effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese Chronic Health Affects:poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have shown manganese may decrease fertility in men. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder. If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic manganese oxide fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Combustible material. No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store the material in a sealed container. Keep away from heat and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:greenish black pwdr. Molecular Weight:726.71 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization. Conditions to Avoid:none Incompatibility:oxidizing agents and halogens Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, nitrogen oxides and manganese oxide. SECTION 11: Toxicological Information RTECS Data:No information available in RTECS. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available. SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound: See category code N450 for reporting Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

生态学数据: 对水是稍微危害的，若无政府许可，勿将材料排入周围环境。

合成路线

638-38-0 917-23-7 ~98% 58356-65-3

文献：Chatel, Gregory; Goux-Henry, Catherine; Kardos, Nathalie; Suptil, Joel; Andrioletti, Bruno; Draye, Micheline Ultrasonics Sonochemistry, 2012 , vol. 19, # 3 p. 390 - 394

34557-72-7 ~% 58356-65-3

文献：Inorganic Chemistry, , vol. 26, p. 2612 - 2618

917-23-7 6156-78-1 ~% 58356-65-3

文献：Canadian Journal of Chemistry, , vol. 67, p. 545 - 550

917-23-7 638-38-0 ~% 58356-65-3

文献：Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 24, p. 874 - 878 Zhurnal Neorganicheskoi Khimii, , vol. 24, p. 1574 - 1581

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