119060-48-9
119060-48-9结构式
- 常用中文名：4,4,4-三氯丁酸叔丁酯
- 常用英文名：tert-butyl 4,4,4-trichlorobutanoate
- CAS号：119060-48-9
- 分子式：C8H13Cl3O2
- 分子量：247.54700
- 发布时间：2018-08-28 09:55:07
- 更新时间：2024-02-07 06:37:23
| 中文名 | 4,4,4-三氯丁酸叔丁酯 |
|---|---|
| 英文名 | tert-butyl 4,4,4-trichlorobutanoate |
| 英文别名 |
tert-Butyl4,4,4-trichlorobutyrate
Butanoic acid,4,4,4-trichloro-,1,1-dimethylethyl ester |
| 密度 | 1.248g/cm3 |
|---|---|
| 沸点 | 257ºC at 760mmHg |
| 熔点 | 300ºC |
| 分子式 | C8H13Cl3O2 |
| 分子量 | 247.54700 |
| 闪点 | 93.3ºC |
| 精确质量 | 245.99800 |
| PSA | 26.30000 |
| LogP | 3.47850 |
| 蒸汽压 | 0.0149mmHg at 25°C |
| 折射率 | 1.47 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 119060-48-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: < 20 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H13Cl3O2 Molecular Weight: 248 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide, acrid smoke and fumes. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 119060-48-9 unlisted. LD50/LC50: Not available. Carcinogenicity: tert-Butyl 4,4,4-trichlorobutanoate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 119060-48-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 119060-48-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 119060-48-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R36/37/38 |
| 安全声明 (欧洲) | S26-S37/39 |
|
~0%
119060-48-9 |
| 文献：Fedorynski, Michal; Dybowska, Agnieszka; Jonczyk, Andrzej Synthesis, 1988 , # 7 p. 549 - 551 |
|
~51%
119060-48-9 |
| 文献：Fedorynski, Michall Tetrahedron, 1999 , vol. 55, # 20 p. 6329 - 6334 |
|
~8%
119060-48-9
详细
|
| 文献：Dehmlow, Eckehard V.; Wilkenloh, Juergen Chemische Berichte, 1990 , vol. 123, p. 582 - 588 |
