426-79-9

• 常用中文名：四苯基四氟硼酸膦
• 常用英文名：Tetraphenylphosphonium tetrafluoroborate
• CAS号：426-79-9
• 分子式：C₂₄H₂₀BF₄P
• 分子量：426.194
• 发布时间：2018-04-15 08:00:00
• 更新时间：2024-01-17 20:39:14

名称

• 中文名: 四苯基四氟硼酸膦
• 英文名: Tetraphenylphosphonium Tetrafluoroborate
• 中文别名: 四氟硼化四苯基膦
• 英文别名: Tetraphenylphosphonium tetrafluoroborate; EINECS 209-194-3; tetraphenylphosphanium,tetrafluoroborate; MFCD00051889; Tetrakis(phenyl)phosphonium tetrafluoroborate

物化性质

• 熔点: 300ºC
• 分子式: C₂₄H₂₀BF₄P
• 分子量: 426.194
• 精确质量: 426.133179
• PSA: 13.59000
• LogP: 5.60600
• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:5

  4.可旋转化学键数量:4

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:30

  8.表面电荷:0

  9.复杂度:321

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:2

• 更多:

  一、物性数据

  性状：不可用

  密度（g/mL,25/4℃）：不可用

  相对蒸汽密度（g/mL,空气=1）：不可用

  熔点（ºC）：300

  沸点（ºC,常压）：不可用

  沸点（ºC,5.2kPa）：不可用

  折射率：不可用

  闪点（ºC）：不可用

  比旋光度（º）：不可用

  自燃点或引燃温度（ºC）：不可用

  蒸气压（kPa,25ºC）：不可用

  饱和蒸气压（kPa,60ºC）：不可用

  燃烧热（KJ/mol）：不可用

  临界温度（ºC）：不可用

  临界压力（KPa）：不可用

  油水（辛醇/水）分配系数的对数值：不可用

  爆炸上限（%,V/V）：不可用

  爆炸下限（%,V/V）：不可用

  溶解性：不可用

MSDS

Name: Tetraphenylphosphonium tetrafluoroborate Material Safety Data Sheet Synonym: CAS: 426-79-9 Section 1 - Chemical Product MSDS Name:Tetraphenylphosphonium tetrafluoroborate Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 426-79-9 Tetraphenylphosphonium tetrafluorobora 207-044-1 Hazard Symbols: XN Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air). Potential Health Effects Eye: May cause eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 426-79-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: > 300 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C24H20BF4P Molecular Weight: 425.9174 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, exposure to moist air or water. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of phosphorus, carbon dioxide, hydrogen fluoride gas. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 426-79-9 unlisted. LD50/LC50: Not available. Carcinogenicity: Tetraphenylphosphonium tetrafluoroborate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Other No information available. Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 426-79-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 426-79-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 426-79-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 二、毒理学数据： 急性毒性：不可用。 生态学数据: 三、生态学数据： 1、其它有害作用：该物质对环境可能有危害，对水体应给予特别注意。

安全

• 危害码 (欧洲): Xn:Harmful;
• 风险声明 (欧洲): R20/21/22;R36/37/38
• 安全声明 (欧洲): S26-S36/37/39
• 海关编码: 2931900090

合成路线

99506-47-5 ~95% 17819-85-1 85289-43-6 426-79-9 详细

文献：Grushin, Vladimir V.; Demkina, Iraida I.; Tolstaya, Tat'yana P. Inorganic Chemistry, 1991 , vol. 30, p. 1760 - 1765

88242-78-8 ~86% 92-52-4 22784-33-4 426-79-9 详细

文献：Grushin, V. V.; Tolstaya, T. P.; Lisichkina, I. N. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, p. 1957 - 1960 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , vol. 32, p. 2165 - 2168

81353-33-5 ~82% 92-52-4 17157-02-7 426-79-9 详细

文献：Grushin, V. V.; Tolstaya, T. P.; Lisichkina, I. N.; Grishin, Yu. K.; Shcherbina, T. M.; et al. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, p. 429 - 431 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , vol. 32, p. 472 - 473

81353-28-8 ~82% 92-52-4 17830-03-4 426-79-9 详细

文献：Grushin, V. V.; Tolstaya, T. P.; Lisichkina, I. N.; Grishin, Yu. K.; Shcherbina, T. M.; et al. Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, p. 429 - 431 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , vol. 32, p. 472 - 473

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海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%