126275-19-2

• 常用中文名：(R)-(+)-N-烯丙基-α-甲基苄胺
• 常用英文名：(R)-(+)-N-ALLYL-ALPHA-METHYLBENZYLAMINE&
• CAS号：126275-19-2
• 分子式：C₁₁H₁₅N
• 分子量：161.24300
• 发布时间：2018-07-05 12:01:43
• 更新时间：2024-01-03 18:26:19
• 下载msds

名称

• 中文名: (R)-(+)-N-烯丙基-α-甲基苄胺
• 英文名: N-[(1R)-1-phenylethyl]prop-2-en-1-amine
• 中文别名: (R)-(+)-N-烯丙基-Alpha-甲基苄胺
• 英文别名: MFCD03427204; (R)-(+)-N-allyl-|A-methylbenzylamine; ((1R)-1-phenylethyl)prop-2-enylamine; (R)-N-(1-phenylethyl)prop-2-en-1-amine

物化性质

• 密度: 0.919 g/mL at 25ºC(lit.)
• 沸点: 58-59ºC1 mm Hg(lit.)
• 分子式: C₁₁H₁₅N
• 分子量: 161.24300
• 闪点: 187 °F
• 精确质量: 161.12000
• PSA: 12.03000
• LogP: 2.91410
• 蒸汽压: 0.0855mmHg at 25°C
• 折射率: n20/D 1.5145(lit.)
• 分子结构:

  五、分子性质数据：

  1、 摩尔折射率：53.02

  2、 摩尔体积（m³/mol）：176.4

  3、 等张比容（90.2K）：418.8

  4、 表面张力（dyne/cm）：31.7

  5、 极化率（10^-24cm³）：21.02

• 计算化学:

  1.疏水参数计算参考值（XlogP）:2.3

  2.氢键供体数量:1

  3.氢键受体数量:1

  4.可旋转化学键数量:4

  5.互变异构体数量:无

  6.拓扑分子极性表面积12

  7.重原子数量:12

  8.表面电荷:0

  9.复杂度:125

  10.同位素原子数量:0

  11.确定原子立构中心数量:1

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：。

  2. 密度（g/mL,25/4℃）：

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：

  5. 沸点（ºC,常压）：

  6. 沸点（ºC,5.2kPa）：未确定

  7. 折射率：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（kPa,25ºC）：未确定

  12. 饱和蒸气压（kPa,60ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：。

MSDS

Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE : (R)-(+)-N-allyl-α-methylbenzylamine Product name Section2. HAZARDS IDENTIFICATION Classification of the substance or mixture According to Regulation (EC) No1272/2008 Skin corrosion (Category 1B) According to European Directive 67/548/EEC as amended. Causes burns. Label elements Pictogram Signal wordDanger Hazard statement(s) H314Causes severe skin burns and eye damage. Precautionary statement(s) P280Wear protective gloves/ protective clothing/ eye protection/ face protection. P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310Immediately call a POISON CENTER or doctor/ physician. Hazard symbol(s) CCorrosive R-phrase(s) R34Causes burns. S-phrase(s) S23Do not breathe vapour. S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39Wear suitable protective clothing, gloves and eye/face protection. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Other hazards - none Section3. COMPOSITION/INFORMATION ON INGREDIENTS Formula: C11H15N Molecular Weight: 161,24 g/mol CAS-No.EC-No.Index-No.ClassificationConcentration (R)-(+)-N-allyl-α-methylbenzylamine 126275-19-2--Skin Corr. 1B; Eye Dam. 1;- H314 C, R34 For the full text of the H-Statements mentioned in this Section, see Section 16. Section4. FIRST AID MEASURES General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Section5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special protective equipment for fire-fighters Wear self contained breathing apparatus for fire fighting if necessary. Section6. ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions Do not let product enter drains. Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. Section7. HANDLING AND STORAGE Precautions for safe handling Avoid inhalation of vapour or mist. Normal measures for preventive fire protection. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective equipment Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Hand protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Eye protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin and body protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Section9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Formliquid Colourcolourless Safety data pH no data available Melting pointno data available Boiling point58 - 59 °C at 1 hPa - lit. Flash pointno data available Ignition temperature no data available Lower explosion limit no data available Upper explosion limit no data available Density0,919 g/cm3 at 25 °C Water solubilityno data available Section10. STABILITY AND REACTIVITY Chemical stability Stable under recommended storage conditions. Conditions to avoid no data available Materials to avoid Strong oxidizing agents Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx) Section11. TOXICOLOGICAL INFORMATION Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Potential health effects InhalationMay be harmful if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. IngestionMay be harmful if swallowed. Causes burns. SkinMay be harmful if absorbed through skin. Causes skin burns. EyesCauses eye burns. Signs and Symptoms of Exposure Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Additional Information RTECS: Not available Section12. ECOLOGICAL INFORMATION Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available PBT and vPvB assessment no data available Other adverse effects no data available Section13. DISPOSAL CONSIDERATIONS Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Contaminated packaging Dispose of as unused product. Section14. TRANSPORT INFORMATION ADR/RID UN-Number: 2735 Class: 8Packing group: II Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ((R)-(+)-N-allyl-α-methylbenzylamine) IMDG UN-Number: 2735 Class: 8Packing group: IIEMS-No: F-A, S-B Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. ((R)-(+)-N-allyl-α-methylbenzylamine) Marine pollutant: No IATA UN-Number: 2735 Class: 8Packing group: II Proper shipping name: Amines, liquid, corrosive, n.o.s. ((R)-(+)-N-allyl-α-methylbenzylamine) Section15. REGULATORY INFORMATION This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Section16. OTHER INFORMATION Text of H-code(s) and R-phrase(s) mentioned in Section 3 Eye Dam.Serious eye damage H314Causes severe skin burns and eye damage. Skin Corr.Skin corrosion CCorrosive R34Causes burns. Further information Copyright 2010 Co. License granted to make unlimited paper copies for internal use only. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Co., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

安全

• 符号: GHS05
• 信号词: Danger
• 危害声明: H314
• 警示性声明: P280-P305 + P351 + P338-P310
• 个人防护装备: Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
• 危害码 (欧洲): C
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): S23-S26-S45-S36-S37-S39
• 危险品运输编码: UN 2735 8/PG 2
• 海关编码: 2921499090

海关

海关编码	2921499090
中文概述	2921499090 其他芳香单胺及衍生物及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素	品名, 成分含量, 用途
Summary	2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%