1201-68-9

1201-68-9结构式

常用中文名：3-(氯甲基)-5-苯基-1,2,4-恶二唑
常用英文名：3-(chloromethyl)-5-phenyl-1,2,4-oxadiazole
CAS号：1201-68-9
分子式：C₉H₇ClN₂O
分子量：194.61800
发布时间：2018-06-21 17:15:26
更新时间：2024-01-02 12:22:33

中文名	3-(氯甲基)-5-苯基-1,2,4-恶二唑
英文名	3-(Chloromethyl)-5-phenyl-1,2,4-oxadiazole
中文别名	3-(氯甲基)-5-苯基-1,2,4-氧二唑
英文别名	3-Chlormethyl-5-phenyl-1,2,4-oxadiazol 3-chloromethyl-5-phenyl-1,2,4-oxadiazole MFCD00084968 3-(chloromethyl)-5-phenyl-1,2,4-oxadiazol

密度	1.283 g/cm3
沸点	316.9ºC at 760 mmHg
熔点	64ºC
分子式	C₉H₇ClN₂O
分子量	194.61800
闪点	145.5ºC
精确质量	194.02500
PSA	38.92000
LogP	2.47540
蒸汽压	0.000739mmHg at 25°C
折射率	1.56
储存条件	2-8°C，密封，干燥，惰性气体

Name:	3-(Chloromethyl)-5-phenyl-1 2 4-oxadiazole tech Material Safety Data Sheet
Synonym:
CAS:	1201-68-9

Section 1 - Chemical Product MSDS Name:3-(Chloromethyl)-5-phenyl-1 2 4-oxadiazole tech Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
1201-68-9	3-(Chloromethyl)-5-phenyl-1,2,4-oxadia		unlisted

Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1201-68-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 58 - 60 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H7ClN2O
Molecular Weight: 195

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1201-68-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-(Chloromethyl)-5-phenyl-1,2,4-oxadiazole - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1201-68-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1201-68-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1201-68-9 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A

危害码 (欧洲)	C: Corrosive;
风险声明 (欧洲)	R34
安全声明 (欧洲)	S26-S36/37/39-S45
海关编码	2934999090

98-88-4

3272-96-6

~46%

1201-68-9

文献：Chiesi Farmaceutici S.p.A.; AMARI, Gabriele; Pesenti, Cristina; Bossolo, Stefano Patent: US2013/172302 A1, 2013 ; Location in patent: Paragraph 0136; 0137; 0138 ;

1403889-97-3

98-88-4

1201-68-9

文献：US2011/311459 A1, ;

255876-57-4

1201-68-9

文献：CHIESI FARMACEUTICI S.P.A.; AMARI, Gabriele; PESENTI, Cristina; BOSSOLO, Stefano Patent: WO2013/98145 A1, 2013 ; Location in patent: Page/Page column 38-39 ;

3272-96-6

98-88-4

1201-68-9

文献：Journal of Medicinal Chemistry, , vol. 43, # 5 p. 995 - 1010

98-88-4

1201-68-9

文献：WO2013/98145 A1, ;

上游产品 3
98-88-4 3272-96-6 1403889-97-3
下游产品 0

海关编码	2934999090
中文概述	2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素	品名, 成分含量, 用途
Summary	2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1201-68-9	491842-63-8
844499-00-9	306936-06-1
874816-05-4	1039860-29-1
175205-62-6	110704-33-1
166179-37-9	73217-30-8
1158522-08-7	940364-43-2
134104-43-1	131615-57-1
6906-52-1	930439-75-1
1018584-77-4	1375289-11-4
849349-65-1	127437-46-1