10028-15-6

10028-15-6结构式

常用中文名：臭氧
常用英文名：ozone
CAS号：10028-15-6
分子式：O₃
分子量：47.99820
相关类别：无机化工氢、氮、氧等工业气体
发布时间：2018-04-23 08:00:00
更新时间：2024-01-02 20:13:12
抗微生物剂；直接用作水的消毒剂；废水处理剂。FDA 2001年6月准用于肉类、家禽的原料处理、储藏和加工以及初级农产品的制备、包装和储存。

中文名	臭氧
英文名	ozone
英文别名	trioxid-2-en-2-ium-1-ide Ozone Oxygen,mol (O3) Triatomic oxygen Ozon [Polish] Ozon EINECS 233-069-2

密度	1.48g/cm3
沸点	-111.9ºC
熔点	-192.7ºC
分子式	O₃
分子量	47.99820
精确质量	47.98470
PSA	51.21000
LogP	0.10050
外观性状	无色气体或暗蓝色液体
折射率	1.278
储存条件	库房低温,通风,干燥,防火,与还原剂分开存放
稳定性	1.臭氧是比氧更活泼的氧化剂。可以同无机物和有机物（烯烃类双键化合物、芳香族化合物等）进行反应。臭氧易溶于水，在相同条件下，臭氧比空气、氧气在水中的溶解度都大，在0～30℃时要大10倍还多。但随水温升高，溶解度降低。臭氧在水中的分解可由OH－催化作用，经过氧化氢而形成氧。臭氧分解的半衰期随温度升高而减少，随水中ph值升高而减少。它可以吸收太阳辐射中的大部分紫外线，从而保护人类及其他生物，免受紫外线伤害。在空气中有极低浓度的臭氧，具有新鲜气味，使人感到清新，有益健康。 2.长时间吸入较高浓度的臭氧会引起呼吸道和眼睛刺激。严重时会损伤肺部组织，并引起胸闷、头痛。工作环境应通风良好，工作人员应穿戴好防护用具，避免臭氧伤害，严重时关闭臭氧发生源。 3.对所有黏膜具有强烈的刺激性，浓度大于0.1 μL/L就有很高的毒性。当臭氧浓度在0.1 μL/L时会有特征的气味。所有操作都必须在通风橱，并且应该有硫代硫酸钠溶液以消耗过量的臭氧。液态臭氧具有强烈的爆炸性。
计算化学	1.疏水参数计算参考值（XlogP）:-1.7 2.氢键供体数量:0 3.氢键受体数量:2 4.可旋转化学键数量:0 5.互变异构体数量:无 6.拓扑分子极性表面积41.1 7.重原子数量:3 8.表面电荷:0 9.复杂度:4.8 10.同位素原子数量:0 11.确定原子立构中心数量:0 12.不确定原子立构中心数量:0 13.确定化学键立构中心数量:0 14.不确定化学键立构中心数量:0 15.共价键单元数量:1
更多	1.性状：无色或者淡蓝色的气体 2.沸点（^oC）：-119 3.熔点（^oC）：-193 4.溶解性：在–80 ~ –100 ^oC左右，在烃类溶剂中的溶解质量分数为0.1%~0.3%。

第一部分：化学品名称

化学品中文名称：	臭氧
化学品英文名称：	Ozone；Triatomic oxygen
中文俗名或商品名：
Synonyms：
CAS No.：	10028-15-6
分子式：	O₃
分子量：	48.00

第二部分：成分/组成信息

纯化学品混合物

化学品名称：臭氧

有害物成分

含量

CAS No.

第三部分：危险性概述

危险性类别：
侵入途径：	吸入
健康危害：	本品具有强氧化能力，对眼睛结膜和整个呼吸道有直接刺激作用。吸入后引起咳嗽、咯痰、胸部紧束感，高浓度吸入引起肺水肿，长期接触可引起支气管炎，细支气管炎，甚至并发肺硬化。
环境危害：
燃爆危险：	本品助燃，具刺激性。

第四部分：急救措施

皮肤接触：
眼睛接触：
吸入：	迅速脱离现场至空气新鲜处。保持呼吸道通畅。呼吸困难时给输氧。呼吸停止时，立即进行人工呼吸。就医。
食入：

第五部分：消防措施

危险特性：	具有强氧化性。与易燃物(如苯)和有机物(如糖、纤维素等)接触会发生剧烈反应，甚至引起燃烧。受热，接触明火、高热或受到摩擦震动、撞击时可发生爆炸。
有害燃烧产物：	氧气。
灭火方法及灭火剂：	切断气源。喷水冷却容器，可能的话将容器从火场移至空旷处。
消防员的个体防护：	消防人员须佩戴防毒面具、穿全身消防服，在上风向灭火。迅速切断气源，用水喷淋保护切断气源的人员，然后根据着火原因选择适当灭火剂灭火。尽可能将容器从火场移至空旷处。喷水保持火场容器冷却，直至灭火结束。
禁止使用的灭火剂：
闪点(℃)：	无意义
自燃温度(℃)：	引燃温度(℃)：无意义
爆炸下限[%(V/V)]：	无意义
爆炸上限[%(V/V)]：	无意义
最小点火能(mJ)：
爆燃点：
爆速：
最大燃爆压力(MPa)：
建规火险分级：

第六部分：泄漏应急处理

应急处理：

切断火源。切断气源，勿使泄漏物与可燃物质(木材、纸、油等)接触，抽排(室内)或强力通风(室外)。漏气容器不能再用，且要经过技术处理以清除可能剩下的气体。

第七部分：操作处置与储存

操作注意事项：

密闭操作，全面通风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴自吸过滤式防毒面具（全面罩），戴化学安全防护眼镜，穿防毒物渗透工作服，戴橡胶手套。远离火种、热源，工作场所严禁吸烟。远离易燃、可燃物。防止气体泄漏到工作场所空气中。避免与还原剂接触。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。

储存注意事项：

储存于阴凉、通风的库房。远离火种、热源。应与易（可）燃物、还原剂等分开存放，切忌混储。储区应备有泄漏应急处理设备。

第八部分：接触控制/个体防护

最高容许浓度：	中国 MAC：0．3mg／m3 前苏联MAC；0．1mg／m3 美国TLV—TWA：ACG
监测方法：
工程控制：	生产过程密闭，全面通风。
呼吸系统防护：	空气中浓度超标时，必须佩戴防毒面具。
眼睛防护：	必要时戴化学安全防护眼镜。
身体防护：	穿工作服。
手防护：	必要时戴防护手套。
其他防护：	工作现场严禁吸烟。保持良好的卫生习惯。

第九部分：理化特性

外观与性状：	无色气体，有特殊的怪味，液态臭氧呈深蓝色，固态的呈紫黑色，在室温下会慢慢分解。
pH：
熔点(℃)：	-193
沸点(℃)：	-112
相对密度(水=1)：	1．71(-183℃)
相对蒸气密度(空气=1)：
饱和蒸气压(kPa)：
燃烧热(kJ/mol)：
临界温度(℃)：
临界压力(MPa)：
辛醇/水分配系数的对数值：
闪点(℃)：	无意义
引燃温度(℃)：	引燃温度(℃)：无意义
爆炸上限%(V/V)：	无意义
爆炸下限%(V/V)：	无意义
分子式：	O₃
分子量：	48.00
蒸发速率：
粘性：
溶解性：	不溶于水。
主要用途：	用于水的消毒和空气的臭氧化，在化学工业中用作强氧化剂。

第十部分：稳定性和反应活性

稳定性：	在常温常压下不稳定
禁配物：	易燃或可燃物、还原剂、活性金属粉末。
避免接触的条件：
聚合危害：	不能出现
分解产物：	氧气。

第十一部分：毒理学资料

急性毒性：
急性中毒：
慢性中毒：
亚急性和慢性毒性：
刺激性：
致敏性：
致突变性：
致畸性：
致癌性：

第十二部分：生态学资料

生态毒理毒性：
生物降解性：
非生物降解性：
生物富集或生物积累性：

第十三部分：废弃处置

废弃物性质：
废弃处置方法：	废气直接排入大气。
废弃注意事项：

第十四部分：运输信息

危险货物编号：
UN编号：
包装标志：
包装类别：
包装方法：
运输注意事项：	储存于通风、低温的库房内。远离火种、热源。包装要求密封，不可与空气接触。应与易燃、可燃物分开存放。搬运时要轻装轻卸，防止包装及容器损坏。禁止撞击和震荡。采用刚瓶运输时必须戴好钢瓶上的安全帽。钢瓶一般平放，并应将瓶口朝同一方向，不可交叉；高度不得超过车辆的防护栏板，并用三角木垫卡牢，防止滚动。严禁与易燃物或可燃物、还原剂、食用化学品等混装混运。夏季应早晚运输，防止日光曝晒。公路运输时要按规定路线行驶，禁止在居民区和人口稠密区停留。铁路运输时要禁止溜放。
RETCS号：
IMDG规则页码：

第十五部分：法规信息

国内化学品安全管理法规：	化学危险物品安全管理条例 (1987年2月17日国务院发布)，化学危险物品安全管理条例实施细则 (化劳发[1992] 677号)，工作场所安全使用化学品规定 ([1996]劳部发423号)等法规，针对化学危险品的安全使用、生产、储存、运输、装卸等方面均作了相应规定。
国际化学品安全管理法规：

第十六部分：其他信息

参考文献：	1.周国泰，化学危险品安全技术全书，化学工业出版社，1997 2.国家环保局有毒化学品管理办公室、北京化工研究院合编，化学品毒性法规环境数据手册，中国环境科学出版社.1992 3.Canadian Centre for Occupational Health and Safety,CHEMINFO Database.1998 4.Canadian Centre for Occupational Health and Safety, RTECS Database, 1989
填表时间：	年月日
填表部门：
数据审核单位：
修改说明：
其他信息：	4
MSDS修改日期：	年月日

毒理学数据:

吸入-大鼠 LC50: 4800 PPM/4小时; 吸入-小鼠 LC50:12.6 ppm/3小时

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RS8225000

CHEMICAL NAME :: Ozone

CAS REGISTRY NUMBER :: 10028-15-6

LAST UPDATED :: 199712

DATA ITEMS CITED :: 97

MOLECULAR FORMULA :: O3

MOLECULAR WEIGHT :: 48.00

WISWESSER LINE NOTATION :: O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 50 ppm/30M

TOXIC EFFECTS :: Behavioral - headache Vascular - BP lowering not characterized in autonomic section Lungs, Thorax, or Respiration - dyspnea

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human - man

DOSE/DURATION :: 80 ppb/6.6H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - respiratory depression Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 100 ppm/1M

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Skin and Appendages - dermatitis, other (after systemic exposure)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human - man

DOSE/DURATION :: 1860 ppb/75M

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Cardiac - pulse rate Lungs, Thorax, or Respiration - cough

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 1 ppm

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 600 ppb/2H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - cough Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4800 ppb/4H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema Blood - hemorrhage

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 12600 ppb/3H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema Blood - hemorrhage

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - cat

DOSE/DURATION :: 34500 ppb/3H

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 36 ppm/3H

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 24800 ppb/3H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - hamster

DOSE/DURATION :: 10500 ppb/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 950 ppb/8H/90D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1600 ug/m3/24H/7D-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Lungs, Thorax, or Respiration - changes in lung weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other oxidoreductases

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 800 ug/m3/24H/3D-C

TOXIC EFFECTS :: Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other oxidoreductases Biochemical - Metabolism (Intermediary) - other proteins

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 700 ppb/2H/28D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - respiratory depression Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 200 ppb/24H/12W-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - cytochrome oxidases (including oxidative phosphorylation) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other oxidoreductases

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 750 ppb/24H/14D-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Blood - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 400 ppb/24H/14D-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Endocrine - changes in thymus weight Immunological Including Allergic - decrease in humoral immune response

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1 ppm/24H/4W-C

TOXIC EFFECTS :: Endocrine - changes in thymus weight Immunological Including Allergic - decrease in humoral immune response Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 608 ug/m3/26W-I

TOXIC EFFECTS :: Endocrine - changes in spleen weight

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Primate - monkey

DOSE/DURATION :: 1500 pph/8H/21D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes Biochemical - Metabolism (Intermediary) - lipids including transport

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Primate - monkey

DOSE/DURATION :: 400 ppb/8H/90D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - fibrosis (interstitial)

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 100 ppb/2H/13D-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 2 ppm/2D-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - changes in lung weight Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 800 ug/m3/24H/3D-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - changes in lung weight Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases Biochemical - Metabolism (Intermediary) - other proteins

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 3 mg/m3/24H/7D-C

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - dehydrogenases

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 5 ppm/2H/75D-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :: TC - Toxic concentration (other than lowest)

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 608 ug/m3/24W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :: TC - Toxic concentration (other than lowest)

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1 ppm/6H/2Y-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 1040 ppb/24H

SEX/DURATION :: female 6-9 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - musculoskeletal system

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

DOSE :: 1500 ppb/24H

SEX/DURATION :: female 17-20 day(s) after conception

TOXIC EFFECTS :: Reproductive - Effects on Newborn - behavioral Reproductive - Effects on Newborn - physical

TYPE OF TEST :: Dominant lethal test

TYPE OF TEST :: Cytogenetic analysis

TYPE OF TEST :: Cytogenetic analysis

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Bird - chicken Fibroblast

REFERENCE :: ZEKBAI Zeitschrift fuer Krebsforschung. (Berlin, Fed. Rep. Ger.) V.1-75, 1903-71. For publisher information, see JCROD7. Volume(issue)/page/year: 67,113,1965 *** REVIEWS *** ACGIH TLV-TWA 0.20 mg/m3 (0.1 ppm), light work DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.16 mg/m3 (0.08 ppm), mod work 85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,1/BEI,1997 ACGIH TLV-TWA 0.1 mg/m3 (0.05 ppm), heavy work 85INA8 "Documentation of the Threshold Limit Values and Biological Exposure Indices," 5th ed., Cincinnati, OH, American Conference of Governmental Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 6,1/BEI,1997 TOXICOLOGY REVIEW FEPRA7 Federation Proceedings, Federation of American Societies for Experimental Biology. (Bethesda, MD) V.1-46, 1942-87. Volume(issue)/page/year: 35,89,1976 TOXICOLOGY REVIEW NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB228-002 TOXICOLOGY REVIEW AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 16,903,1968 TOXICOLOGY REVIEW NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: CONF-691001 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 ppm (0.2 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,194,1971 OSHA PEL (Gen Indu):8H TWA 0.1 ppm (0.2 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 ppm (0.2 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 ppm (0.2 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 ppm (0.2 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.1 ppm (0.02 mg/m3) JAN 1993 OEL-AUSTRALIA:TWA 0.1 ppm (0.2 mg/m3);STEL 0.3 ppm (0.6 mg/m3) JAN 1993 OEL-BELGIUM:STEL 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-DENMARK:TWA 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-FINLAND:TWA 0.1 ppm (0.2 mg/m3);STEL 0.3 ppm (0.6 mg/m3) JAN 1993 OEL-FRANCE:TWA 0.1 ppm (0.2 mg/m3);STEL 0.2 ppm (0.4 mg/m3) JAN 1993 OEL-GERMANY:TWA 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-HUNGARY:TWA 0.2 mg/m3;STEL 0.4 mg/m3 JAN 1993 OEL-JAPAN:TWA 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-POLAND:TWA 0.1 mg/m3 JAN 1993 OEL-RUSSIA:TWA 0.1 ppm;STEL 0.1 mg/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 ppm (0.2 mg/m3);STEL 0.3 ppm (0.6 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.1 ppm (0.2 mg/m3);STEL 0.2 ppm (0.4 mg/m3) JAN 1993 OEL-TURKEY:TWA 0.1 ppm (0.2 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 ppm (0.2 mg/m3);STEL 0.3 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO OZONE-air:CL 0.1 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81651 No. of Facilities: 6329 (estimated) No. of Industries: 54 No. of Occupations: 53 No. of Employees: 32552 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81651 No. of Facilities: 5347 (estimated) No. of Industries: 70 No. of Occupations: 67 No. of Employees: 72134 (estimated) No. of Female Employees: 32361 (estimated)

危害码 (欧洲)	Xi
风险声明 (欧洲)	R10:Flammable. R37:Irritating to the respiratory system.
安全声明 (欧洲)	S16:Keep away from sources of ignition - No smoking .
危险品运输编码	1956
WGK德国	3
RTECS号	DC3300000
包装等级	III
危险类别	2.2

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