(11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺

更新时间:2024-01-06 15:08:26

(11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺结构式
(11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺结构式
品牌特惠专场
常用名 (11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺 英文名 (11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS号 497883-22-4 分子量 539.603
密度 N/A 沸点 710.7±63.0 °C at 760 mmHg
分子式 C36H30NO2P 熔点 102-103°C
MSDS N/A 闪点 383.6±33.7 °C

 名称

中文名 (11bS)-N,N-双[(R)-1-苯基乙基]-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺
英文名 N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
英文别名 更多

 物理化学性质

沸点 710.7±63.0 °C at 760 mmHg
熔点 102-103°C
分子式 C36H30NO2P
分子量 539.603
闪点 383.6±33.7 °C
精确质量 539.201416
LogP 10.33
蒸汽压 0.0±2.3 mmHg at 25°C
储存条件 室温,干燥

 安全信息

个人防护装备 Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
危险品运输编码 NONH for all modes of transport

 文献4

更多文献
Tandem asymmetric conjugate addition--silylation of enantiomerically enriched zinc enolates. Synthetic importance and mechanistic implications.

Org. Lett. 4 , 3835, (2002)

[formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, ...

Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to (2-pyridyl)sulfonyl imines of chalcones.

J. Org. Chem. 70 , 7451, (2005)

[reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reage...

Synlett , 1375, (2001)

 英文别名

N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]-
MFCD08561138
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine