methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate

Modify Date: 2024-01-28 17:03:15

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure
methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate structure
Common Name methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate
CAS Number 112196-58-4 Molecular Weight 423.61800
Density 1.03g/cm3 Boiling Point 459.7ºC at 760 mmHg
Molecular Formula C22H37NO5Si Melting Point N/A
MSDS N/A Flash Point 231.8ºC

 Names

Name methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.03g/cm3
Boiling Point 459.7ºC at 760 mmHg
Molecular Formula C22H37NO5Si
Molecular Weight 423.61800
Flash Point 231.8ºC
Exact Mass 423.24400
PSA 65.07000
LogP 5.02160
Vapour Pressure 1.23E-08mmHg at 25°C
Index of Refraction 1.488

 Synthetic Route

~88%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Boger; Yohannes Journal of Organic Chemistry, 1988 , vol. 53, # 3 p. 487 - 499

~94%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Yokokawa, Fumiaki; Inaizumi, Akiko; Shioiri, Takayuki Tetrahedron, 2005 , vol. 61, # 6 p. 1459 - 1480

~%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Journal of Organic Chemistry, , vol. 53, # 3 p. 487 - 499

~%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Journal of Organic Chemistry, , vol. 53, # 3 p. 487 - 499

~%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Journal of Organic Chemistry, , vol. 53, # 3 p. 487 - 499

~%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Tetrahedron, , vol. 61, # 6 p. 1459 - 1480

~%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Tetrahedron, , vol. 61, # 6 p. 1459 - 1480

~%

methyl (2S)-3-[4-[tert-butyl(dimethyl)silyl]oxyphenyl]-2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]propanoate Structure

methyl (2S)-3-[...

CAS#:112196-58-4

Literature: Tetrahedron, , vol. 61, # 6 p. 1459 - 1480

 Synonyms

N-[(1,1-dimethylethoxy)carbonyl]-O-[(1,1-dimethylethyl)dimethylsilyl]-N-methyl-L-tyrosine Methyl Ester
Boc-(S)-N-MeTyr(TBS)-OMe
O-tert-Butyldimethylsilyl-N-methyl-N-t-butoxycarbonyl-L-tyrosine,Methyl Ester