tert-Butyldimethylsilyl chloride

Modify Date: 2024-01-02 08:33:38

tert-Butyldimethylsilyl chloride Structure
tert-Butyldimethylsilyl chloride structure
Common Name tert-Butyldimethylsilyl chloride
CAS Number 18162-48-6 Molecular Weight 150.722
Density 0.9±0.1 g/cm3 Boiling Point 125.0±0.0 °C at 760 mmHg
Molecular Formula C6H15ClSi Melting Point 86-89 °C
MSDS Chinese USA Flash Point 22.8±0.0 °C
Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger

 Names

Name tert-butyldimethylsilyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 125.0±0.0 °C at 760 mmHg
Melting Point 86-89 °C
Molecular Formula C6H15ClSi
Molecular Weight 150.722
Flash Point 22.8±0.0 °C
Exact Mass 150.063156
LogP 3.40
Vapour Pressure 15.0±0.2 mmHg at 25°C
Index of Refraction 1.411
Storage condition Store at 5°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VV2000000
CHEMICAL NAME :
Silane, t-butylchlorodimethyl-
CAS REGISTRY NUMBER :
18162-48-6
BEILSTEIN REFERENCE NO. :
0505999
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C6-H15-Cl-Si
MOLECULAR WEIGHT :
150.75
WISWESSER LINE NOTATION :
G-SI-1&1&X1&1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Immunological Including Allergic - decreased immune response
REFERENCE :
StoGD# Personal Communication from G.D. Stoner, Dept. of Community Medicine, School of Medicine, Univ. of California, La Jolla, CA 92037, May 25, 1975 Volume(issue)/page/year: 27MAY1975

 Safety Information

Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger
Hazard Statements H225-H304-H314-H336-H361d-H373
Supplemental HS May form explosive peroxides.
Precautionary Statements P210-P261-P280-P301 + P310-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R10;R34
Safety Phrases S26-S36/37/39-S46-S62-S45-S25-S16-S28-S27-S33-S29-S53
RIDADR UN 2925 4.1/PG 2
WGK Germany 2
RTECS VV2000000
Packaging Group III
Hazard Class 4.1
HS Code 29310095

 Synthetic Route

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles26

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Determination of low levels of benzodiazepines and their metabolites in urine by hollow-fiber liquid-phase microextraction (LPME) and gas chromatography-mass spectrometry (GC-MS).

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In this work a multivariate statistical tool (Derringer and Suich optimization) was proposed for the separation of seventeen capsinoids (natural and synthetic) using the UHPLC-DAD chromatography. Caps...

 Synonyms

Silane, chloro-tert-butyldimethyl-
tert-Butyldimethylsilyl chloride
t-butyldimethylchlorosilane
Silane, chloro(1,1-dimethylethyl)dimethyl-
TBDMSCl
TBUME2SI-CL
tbdmschloride
tert-butyldimethylsilylchloride
EINECS 242-042-4
tert-Butyldimethylsilyl chloride
TBDMCl
TBDMS chloride
tert-butyl(chloro)dimethylsilane
tert-Butyl(chloro)dimethylsilane,tert-Butyldimethylchlorosilane,TBDMSCl
tert-Butyldim
Butyldimethylsilyl chloride
MFCD00000501
tert-Butyldimethylchlorosilane [tert-Butyldimethylsilylating Agent]
tert-Butyldimethylchlorosilane
BDCS
TBDMSCI
TBSCL
Chloro(dimethyl)(2-methyl-2-propanyl)silane
SILANE TBM2
CB2790
Silane, t-butylchlorodimethyl-
tert-Butylchlorodimethylsilane
TBDMCS
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