Tracking juniper berry content in oils and distillates by spectral deconvolution of gas chromatography/mass spectrometry data.

Albert Robbat, Amanda Kowalsick, Jessalin Howell

Index: J. Chromatogr. A. 1218(32) , 5531-41, (2011)

Full Text: HTML

Abstract

The complex nature of botanicals and essential oils makes it difficult to identify all of the constituents by gas chromatography/mass spectrometry (GC/MS) alone. In this paper, automated sequential, multidimensional gas chromatography/mass spectrometry (GC-GC/MS) was used to obtain a matrix-specific, retention time/mass spectrometry library of 190 juniper berry oil compounds. GC/MS analysis on stationary phases with different polarities confirmed the identities of each compound when spectral deconvolution software was used to analyze the oil. Also analyzed were distillates of juniper berry and its oil as well as gin from four different manufacturers. Findings showed the chemical content of juniper berry can be traced from starting material to final product and can be used to authenticate and differentiate brands.Copyright © 2011 Elsevier B.V. All rights reserved.