2-(HYDROXYMETHYL)ANTHRAQUINONE

Names

[ Name ]:
2-(HYDROXYMETHYL)ANTHRAQUINONE

[Synonym ]:
9,10-Anthracenedione, 2-(hydroxymethyl)-
2-(Hydroxymethyl)-9,10-anthraquinone
2-(hydroxymethyl)anthracene-9,10-dione
EINECS 241-274-3
MFCD00001236
2-(HYDROXYMETHYL)ANTHRAQUINONE
2-Hydroxy methyl anthraquinone

Biological Activity

[Description]:

2-(Hydroxymethyl)anthraquinone is used as a photoremovable protecting group (PRPG) to chemically cage sex pheromone (e.g. (Z)-11-hexadecen-1-ol (sex pheromone of Chilo infuscatellussnellen))[1].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Sanghamitra Atta, et al. Photoremovable protecting groups as controlled-release device for sex pheromone. Photochem Photobiol Sci. 2013 Feb;12(2):393-403

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
472.9±34.0 °C at 760 mmHg

[ Melting Point ]:
192-197 °C(lit.)

[ Molecular Formula ]:
C₁₅H₁₀O₃

[ Molecular Weight ]:
238.238

[ Flash Point ]:
253.9±22.2 °C

[ Exact Mass ]:
238.062988

[ PSA ]:
54.37000

[ LogP ]:
2.20

[ Appearance of Characters ]:
light yellow

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.677

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CB7600000

CHEMICAL NAME :: Anthraquinone, 2-(hydroxymethyl)-

CAS REGISTRY NUMBER :: 17241-59-7

BEILSTEIN REFERENCE NO. :: 2120452

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C15-H10-O3

MOLECULAR WEIGHT :: 238.25

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Unscheduled DNA synthesis

TEST SYSTEM :: Rodent - rat Liver

DOSE/DURATION :: 10 mg/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 240,1,1990

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
CB7600000

[ HS Code ]:
2914690090

Customs

[ HS Code ]: 2914690090

[ Summary ]:
2914690090 other quinones。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

[Studies on the chemical constituents from stem of Chirita longgangensis var. Hongyao].

Zhongguo Zhong Yao Za Zhi 31(4) , 307-8, (2006)

To isolate and elucidate the constituents from stem of Chirita longgangensis var. hongyao.The constituents were extracted with methanol and isolated by chromatography on silica gel, Sephadex LH-20 and...

Photoremovable protecting groups as controlled-release device for sex pheromone.

Photochem. Photobiol. Sci. 12(2) , 393-403, (2013)

Photoremovable protecting groups (PRPGs) were demonstrated as a delivery device for controlled release of pheromone under both UV light (≥350 nm) and direct sunlight irradiation. In the present work, ...

Short-chain analogs of luteinizing hormone-releasing hormone containing cytotoxic moieties.

Proc. Natl. Acad. Sci. U. S. A. 89(21) , 10203-7, (1992)

Five hexapeptide and heptapeptide analogs of luteinizing hormone-releasing hormone (LH-RH) were synthesized for use as carriers for cytotoxic compounds. These short analogs were expected to enhance ta...