indium(iii) isopropoxide

Names

[ Name ]:
indium(iii) isopropoxide

[Synonym ]:
MFCD00210318

Biological Activity

[Description]:

Indium(III) Isopropoxide is an organo-metallic compound. Indium(III) Isopropoxide uesd as a hydrogen transfer catalyst for conversion of benzylic alcohols into aldehydes or ketones via Oppenauer oxidation. Indium(III) Isopropoxide also can be used as metal precursor[1][2].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[In Vitro]

Indium(III) isopropoxide as an Oppenaueroxidation catalyst, and the conversion of primary or secondary alcohols into the corresponding aldehydes or ketones was promoted at room temperature using pivalaldehyde as an oxidant[1].

[References]

[1]. Yohei Ogiwara, et al. Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation. Synthesis. 2016, 48(23): 4143-4148.

[2]. Daniela Caruntu, et al. One-Step Synthesis of Nearly Monodisperse, Variable-Shaped In 2 O 3 Nanocrystals in Long Chain Alcohol Solutions. The Journal of Physical Chemistry C. March 2010, 114(11):4875-4886.

Chemical & Physical Properties

[ Density]:
0.808 g/mL at 25ºC

[ Boiling Point ]:
82℃

[ Melting Point ]:
145ºC (dec.)

[ Molecular Formula ]:
C₃H₈O_.1/₃In

[ Molecular Weight ]:
292.07900

[ Flash Point ]:
10ºC

[ Exact Mass ]:
292.05300

[ PSA ]:
69.18000

[ LogP ]:
2.47590

[ Index of Refraction ]:
n20/D1.383

[ Water Solubility ]:
Soluble in alcohols, ketones and esters.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H319-H336

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
36/37/38-41-11

[ Safety Phrases ]:
26-36/37/39-36-33-16

[ RIDADR ]:
UN 1219 3/PG 2

Articles

Ambient pressure syntheses of size-controlled corundum-type In2O3 nanocubes.

J. Am. Chem. Soc. 29th ed., 128 , 9326, (2006)

Hydrolysis of In(O-iPr)3 by 10 molar excess of water at 90 degrees C in a surfactant/solvent mixture of oleylamine/oleic acid/trioctylamine provides very small nanoparticles (<5 nm in diameter) of In(...

Caruntu, D.; et al.

J. Phys. Chem. C Nanomater. Interfaces 11th ed., 114 , 4875, (2010)