3,5-Bis(trifluoromethyl)benzene-1-sulfonyl chloride

Names

[ Name ]:
3,5-Bis(trifluoromethyl)benzene-1-sulfonyl chloride

[Synonym ]:
3,5-bis(trifluoromethyl)benzene sulfonyl chloride
EINECS 254-371-0
3,5-Bis(trifluoromethyl)benzene-1-sulfonyl chloride
MFCD00014725
WSGR CXFFF EXFFF
Benzenesulfonyl chloride, 3,5-bis(trifluoromethyl)-
3,5-(bistrifluoromethyl)phenylsulfonyl chloride
3,5-Bis(trifluoromethyl)benzenesulphonyl chloride
3,5-di(trifluoromethyl)benzenesulfonyl chloride
3,5-Di(trifluoromethyl)benzene-1-sulfonyl chloride
3,5-Bis(trifluoromethyl)benzenesulfonyl chloride

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
248.3±40.0 °C at 760 mmHg

[ Melting Point ]:
34-38 °C(lit.)

[ Molecular Formula ]:
C₈H₃ClF₆O₂S

[ Molecular Weight ]:
312.617

[ Flash Point ]:
104.0±27.3 °C

[ Exact Mass ]:
311.944641

[ PSA ]:
42.52000

[ LogP ]:
4.07

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.435

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

New library of aminosulfonyl-tagged Hoveyda-Grubbs type complexes: Synthesis, kinetic studies and activity in olefin metathesis transformations.

Beilstein J. Org. Chem. 6 , 1159-66, (2010)

Seven novel Hoveyda-Grubbs precatalysts bearing an aminosulfonyl function are reported. Kinetic studies indicate an activity enhancement compared to Hoveyda's precatalyst. A selection of these catalys...

Highly enantioselective catalytic thiolysis of prochiral cyclic dicarboxylic anhydrides utilizing a bifunctional chiral sulfonamide.

Angew. Chem. Int. Ed. Engl. 44(36) , 5838-41, (2005)

Versatile chiral reagent for the highly enantioselective synthesis of either anti or syn ester aldols. Corey EJ and Kim SS.

J. Am. Chem. Soc. 112(12) , 4976-4977, (1990)