1-ADAMANTYLOXYCARBONYL FLUORIDE

[ Density]:
1.2g/cm3

[ Boiling Point ]:
253.2ºC at 760 mmHg

[ Melting Point ]:
30-32ºC(lit.)

[ Molecular Formula ]:
C₁₁H₁₅FO₂

[ Molecular Weight ]:
198.23400

[ Flash Point ]:
192 °F

[ Exact Mass ]:
198.10600

[ PSA ]:
26.30000

[ LogP ]:
3.06130

[ Index of Refraction ]:
1.503

[ Storage condition ]:
2-8°C

Click to get detail MSDS

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 2921 8/PG 1

[ HS Code ]:
2915900090

Click to get detail synthetic route

Precursor

DownStream

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

[1-Adamanty fluoroformate, a useful reagent in peptide chemistry (author's transl)].

Hoppe. Seylers. Z. Physiol. Chem. 357 , 1647, (1976)

1-Adamantyl fluoroformate was prepared from 1-adamantol and fluorophosgene. The cristalline and stable fluoroformate was allowed to react with amino acids to give the corresponding 1-adamantyloxycarbo...

G.W. Kenner et al.

Tetrahedron 35 , 2767, (1979)

I.J. Galpin et al.

Tetrahedron 35 , 2771, (1979)

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