RuPhos

Names

[ Name ]:
RuPhos

[Synonym ]:
2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl
Dicyclohexyl(2',6'-diisopropoxy-2-biphenylyl)phosphine
Phosphine, [2',6'-bis(1-methylethoxy)[1,1'-biphenyl]-2-yl]dicyclohexyl-
Ru Phos
MFCD06798294
2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl
Dicyclohexyl(2',6'-diisopropoxybiphenyl-2-yl)phosphine
RuPhos
dicyclohexyl-[2-[2,6-di(propan-2-yloxy)phenyl]phenyl]phosphane
2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl

Biological Activity

[Description]:

RuPhos is a biochemical reagent that can be used as a biological material or organic compound for life science related research.

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

Chemical & Physical Properties

[ Boiling Point ]:
551.7±40.0 °C at 760 mmHg

[ Melting Point ]:
123-124ºC

[ Molecular Formula ]:
C₃₀H₄₃O₂P

[ Molecular Weight ]:
466.63

[ Flash Point ]:
360.7±27.6 °C

[ Exact Mass ]:
466.300079

[ PSA ]:
32.05000

[ LogP ]:
9.41

[ Appearance of Characters ]:
Powder | white

[ Vapour Pressure ]:
0.0±1.4 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H332-H413

[ Precautionary Statements ]:
P280

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37-S39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.

Acc. Chem. Res. 41 , 1461, (2008)

The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucia...

Biaryl phosphane ligands in palladium-catalyzed amination.

Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008)

Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have pr...

Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.

Chem. Sci. 2 , 27, (2011)

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of th...