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13201-46-2

13201-46-2 structure
13201-46-2 structure
  • Name: tiglic acid
  • Chemical Name: 2-methylbut-2-enoic acid
  • CAS Number: 13201-46-2
  • Molecular Formula: C5H8O2
  • Molecular Weight: 100.11600
  • Create Date: 2018-08-14 11:02:11
  • Modify Date: 2024-01-10 23:17:21

Name 2-methylbut-2-enoic acid
Synonyms dimethylphenylacetoaldehyde
TIGLIC ACID
2-METHYLBUT-2-ENOICACID
2-BUTENOIC ACID,2-METHYL-
2,3-dimethylacrylic acid
2-METHYLBUT-2-ENOIC ACID
3,4-dimethylacetophenone
3-acetyl-1,2-dimethylbenzene
Dimethyl-4-phenylenediamine
2',3'-dimethyl-acetophenone
2-methyl but-2-enoic acid
2-METHYL-2-BUTENOIC ACID
methylmethacrylic acid
Density 1.01g/cm3
Boiling Point 95-96ºC12 mm Hg(lit.)
Melting Point 61-64ºC(lit.)
Molecular Formula C5H8O2
Molecular Weight 100.11600
Flash Point 96ºC
Exact Mass 100.05200
PSA 37.30000
LogP 1.03720
Vapour Pressure 0.152mmHg at 25°C
Index of Refraction 1.45
Name: 2-Methylbut-2-enoic acid 97% Material Safety Data Sheet
Synonym: 2,3-Dimethylacrylic aci
CAS: 13201-46-2
Section 1 - Chemical Product MSDS Name:2-Methylbut-2-enoic acid 97% Material Safety Data Sheet
Synonym:2,3-Dimethylacrylic aci

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13201-46-2 2-Methylbut-2-enoic acid 97% 236-167-3
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13201-46-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white crystalline solid
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 95 - 96 deg C @11.5mmHg
Freezing/Melting Point: 63 - 64 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H8O2
Molecular Weight: 100

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13201-46-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Methylbut-2-enoic acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13201-46-2: No information available.
Canada
CAS# 13201-46-2 is listed on Canada's DSL List.
CAS# 13201-46-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13201-46-2 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases 26-36/37/39-45
RIDADR UN 3261 8/PG 2
HS Code 2916190090
HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%