4261-68-1

4261-68-1 structure
4261-68-1 structure

Name 2-Diisopropylaminoethyl chloride hydrochloride
Synonyms 2-Diisopropylaminoet
Deticen
2-Propanamine, N-(2-chloroethyl)-N-(1-methylethyl)-, hydrochloride (1:1)
2-Diisopropylaminoethylchloride HCl
n-(2-chloroethyl)-n-isopropylpropan-2-aminium chloride
DIISOPROPYLAMINOETHYL CHLORIDE HCL
MFCD00012496
N-(2-chloroethyl)-N-(propan-2-yl)propan-2-amine hydrochloride (1:1)
i-Pr2NCH2CH2Cl
DIC hydrochloride
N,N-Diisopropylaminoethyl chloride HCI
2-chloroethyldiisopropylammonium chloride
EINECS 224-238-1
N-(2-Chloroethyl)-N-isopropylpropan-2-amine hydrochloride (1:1)
Dacatic
2-Propanamine, N- (2-chloroethyl)-N-(1-methylethyl)-, hydrochloride
N-(2-Chloroethyl)-N-isopropyl-2-propanamine hydrochloride (1:1)
Density 0.909g/cm3
Boiling Point 152.7ºC at 760 mmHg
Melting Point 129-132 °C(lit.)
Molecular Formula C8H19Cl2N
Molecular Weight 200.149
Flash Point 46.1ºC
Exact Mass 199.089462
PSA 3.24000
LogP 3.14600
Water Solubility SOLUBLE
Name: 2-(Diisopropylamino)ethyl Chloride Hydro-Chloride 97% Material Safety Data Sheet
Synonym: 2-Chloro-N,N-Diisopropylethylamine Hydrochloride; N-(2-Chloroethyl)diisopropylamine Hydrochloride; DIC
CAS: 4261-68-1
Section 1 - Chemical Product MSDS Name:2-(Diisopropylamino)ethyl Chloride Hydro-Chloride 97% Material Safety Data Sheet
Synonym:2-Chloro-N,N-Diisopropylethylamine Hydrochloride; N-(2-Chloroethyl)diisopropylamine Hydrochloride; DIC

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4261-68-1 2-Diisopropylaminoethyl Chloride Hydro 97 224-238-1
Hazard Symbols: T
Risk Phrases: 23/24/25

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4261-68-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: light beige
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 133 - 135 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: (CH3)2CH!2NCH2CH2Cl.HCl
Molecular Weight: 200.15

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, strong acids, strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 4261-68-1: TX1521900 LD50/LC50:
CAS# 4261-68-1: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, skin: 500 mg/24H Severe; Inhalation, rat: LC50 = 12 mg/m3/4H; Oral, rat: LD50 = 96750 ug/kg; Skin, rabbit: LD50 = 197 mg/kg.
Carcinogenicity:
2-Diisopropylaminoethyl Chloride Hydrochloride - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 4261-68-1: No information available.
Canada
CAS# 4261-68-1 is listed on Canada's NDSL List.
CAS# 4261-68-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4261-68-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes T+:Verytoxic;C:Corrosive;
Risk Phrases R24/25;R26;R36/37/38
Safety Phrases S26-S36/37/39-S45-S38-S28A
RIDADR UN 2811 6.1/PG 1
WGK Germany 3
RTECS TX1521900
Packaging Group I
Hazard Class 6.1
HS Code 29211980

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4261-68-1 structure

4261-68-1

Literature: CHINA PHARMACEUTICAL UNIVERSITY; Xiang, Hua; Wang, Tianlin; Xiao, Hong; You, Qidong; Yao, Yao; Li, Xiaobo; Liao, Qingjiang Patent: US2013/85140 A1, 2013 ; Location in patent: Paragraph 0072; 0073 ;

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4261-68-1 structure

4261-68-1

Literature: Mahmoudkhani, Amir Hossein; Langer, Vratislav Acta Crystallographica Section C: Crystal Structure Communications, 1999 , vol. 55, # 7 p. 1163 - 1167

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4261-68-1 structure

4261-68-1

Literature: Rohrmann; Shonle Journal of the American Chemical Society, 1944 , vol. 66, p. 1640
HS Code 2921199090
Summary 2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%