Name | 1-Chloroethyl ethyl carbonate |
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Synonyms |
1-chloroethy ethyl carbonate
1-Ethoxycarbonyloxyethyl chloride 1-Chloroethylethylcarbonate 1-Chlorodiethyl Carbonate Carbonic Acid 1-Chloroethyl Ethyl Ester Carbonic acid, 1-chloroethyl ethyl ester Carbonic acid ethyl 1-chloroethyl ester EINECS 256-832-1 1-Chloroethyl ethyl carbonate MFCD00040523 ethyl chloroethyl carbonate CEEC Carbonic acid 1-chloroethyl=ethyl |
Density | 1.1±0.1 g/cm3 |
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Boiling Point | 147.5±23.0 °C at 760 mmHg |
Melting Point | 159-161°C |
Molecular Formula | C5H9ClO3 |
Molecular Weight | 152.576 |
Flash Point | 50.0±21.6 °C |
Exact Mass | 152.024017 |
PSA | 35.53000 |
LogP | 1.26 |
Vapour Pressure | 4.4±0.3 mmHg at 25°C |
Index of Refraction | 1.420 |
Storage condition | 2-8°C |
1-Chloroethyl Ethyl Carbonate
Revision number: 5
SAFETY DATA SHEET Section1. IDENTIFICATION Product name:1-Chloroethyl Ethyl Carbonate Revision number:5 Section2. HAZARDS IDENTIFICATION GHS classification PHYSICAL HAZARDS Category 4 Flammable liquids HEALTH HAZARDS Category 2 Skin corrosion/irritation Serious eye damage/eye irritationCategory 2A Not classified ENVIRONMENTAL HAZARDS GHS label elements, including precautionary statements Pictograms or hazard symbols Signal wordWarning Hazard statementsCombustible liquid Causes skin irritation Causes serious eye irritation Precautionary statements: Keep away from flames and hot surfaces. [Prevention] Wash hands thoroughly after handling. Wear protective gloves and eye/face protection. [Response]IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. [Storage]Store in a well-ventilated place. Keep cool. [Disposal]Dispose of contents/container through a waste management company authorized by the local government. Section3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/mixture:Substance Components:1-Chloroethyl Ethyl Carbonate Percent:>98.0%(GC) 50893-36-2 CAS Number: Synonyms:Carbonic Acid 1-Chloroethyl Ethyl Ester , 1-Chlorodiethyl Carbonate 1-Chloroethyl Ethyl Carbonate Section3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Formula:C5H9ClO3 Section4. FIRST AID MEASURES Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. Ingestion: Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air- tight goggles. Section5. FIRE-FIGHTING MEASURES Dry chemical, foam, water spray, carbon dioxide. Suitable extinguishing media: Unsuitable extinguishing Solid streams of water media: Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to from the chemical:generate poisonous fume. Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. In case of fire in the surroundings: Remove movable containers if safe to do so. Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment. equipment for firefighters: Section6. ACCIDENTAL RELEASE MEASURES Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak. protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled emergency procedures: around the leakage area by roping off, etc. Environmental precautions: Prevent product from entering drains. Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust). containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected up: material should be promptly disposed of, in accordance with appropriate laws and regulations. Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in case of a fire. Use spark-proof tools and explosion-proof equipment. hazards: Section7. HANDLING AND STORAGE Precautions for safe handling Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment. Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take measures to prevent the build up of electrostatic charge. Use explosion-proof equipment. Wash hands and face thoroughly after handling. Use a closed system, ventilation. Advice on safe handling: Avoid contact with skin, eyes and clothing. Conditions for safe storage, including any incompatibilities Storage conditions:Keep container tightly closed. Store in a cool, dark and well-ventilated place. Store under inert gas. Protect from moisture. Store away from incompatible materials such as oxidizing agents. Moisture-sensitive Comply with laws. Packaging material: 1-Chloroethyl Ethyl Carbonate Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls:Install a closed system or local exhaust as possible so that workers should not be exposed directly. Also install safety shower and eye bath. Personal protective equipment Respiratory protection: Vapor respirator. Follow local and national regulations. Protective gloves. Hand protection: Eye protection:Safety glasses. A face-shield, if the situation requires. Skin and body protection: Protective clothing. Protective boots, if the situation requires. Section9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C):Liquid Form:Clear Colorless - Slightly pale yellow Colour: Odour:No data available pH: No data available Melting point/freezing point:No data available Boiling point/range:160°C Flash point:62°C Flammability or explosive limits: Lower:No data available Upper:No data available Relative density:1.14 Solubility(ies): No data available [Water] [Other solvents]No data available Section10. STABILITY AND REACTIVITY Chemical stability:Stable under proper conditions. Possibility of hazardous No special reactivity has been reported. reactions: Open flame Conditions to avoid: Incompatible materials: Oxidizing agents Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride products: Section11. TOXICOLOGICAL INFORMATION Acute Toxicity:No data available Skin corrosion/irritation: No data available Serious eyeNo data available damage/irritation: Germ cell mutagenicity: No data available Carcinogenicity: No data available IARC = NTP =No data available Reproductive toxicity:No data available Section12. ECOLOGICAL INFORMATION Ecotoxicity: Fish:No data available Crustacea:No data available Algae:No data available Persistence / degradability: No data available BioaccumulativeNo data available potential(BCF): Mobility in soil 1-Chloroethyl Ethyl Carbonate Section12. ECOLOGICAL INFORMATION Log Pow:No data available Soil adsorption (Koc): No data available Henry's LawNo data available constant(PaM3/mol): Section13. DISPOSAL CONSIDERATIONS Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when disposing of the substance. Section14. TRANSPORT INFORMATION Hazards Class:Does not correspond to the classification standard of the United Nations UN-No:Not listed Section15. REGULATORY INFORMATION Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002 and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were prescribed. SECTION 16 - ADDITIONAL INFORMATION N/A |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | Xi:Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S28 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2920909090 |
~94% 50893-36-2 |
Literature: Barcelo, Gerard; Senet, Jean-Pierre; Sennyey, Gerard; Bensoam, Jean; Loffet, Albert Synthesis, 1986 , # 8 p. 627 - 632 |
~% 50893-36-2 |
Literature: Merck and Co., Inc. Patent: US4426391 A1, 1984 ; |
~62% 50893-36-2 |
Literature: Hatlelid, Jostein; Benneche, Tore; Undheim, Kjell Acta Chemica Scandinavica, 1996 , vol. 50, # 11 p. 1041 - 1044 |
~48% 50893-36-2 |
Literature: Iyer; Yu; Ho; Agrawal Synthetic Communications, 1995 , vol. 25, # 18 p. 2739 - 2749 |
~% 50893-36-2 |
Literature: Mueller,H. Justus Liebigs Annalen der Chemie, 1890 , vol. 258, p. 51,61 |
Precursor 5 | |
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DownStream 9 | |
HS Code | 2920909090 |
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Summary | 2920909090 esters of other inorganic acids of non-metals (excluding esters of hydrogen halides) and their salts; their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |