133232-56-1

133232-56-1 structure
133232-56-1 structure
  • Name: 3-Iodo-2-methylbenzoic acid
  • Chemical Name: 3-Iodo-2-methylbenzoic acid
  • CAS Number: 133232-56-1
  • Molecular Formula: C8H7IO2
  • Molecular Weight: 262.044
  • Create Date: 2018-04-01 08:00:00
  • Modify Date: 2024-01-02 10:57:05

Name 3-Iodo-2-methylbenzoic acid
Synonyms 3-iodo-2-methyl-benzoic acid
3-Iodo-2-methylbenzoic acid
3-Jod-2-methyl-benzoesaeure
benzoic acid, 3-iodo-2-methyl-
2-Carboxy-6-iodotoluene
3-Iodo-o-toluic acid
Benzoic acid,3-iodo-2-methyl
Density 1.9±0.1 g/cm3
Boiling Point 341.8±30.0 °C at 760 mmHg
Melting Point 124-126ºC
Molecular Formula C8H7IO2
Molecular Weight 262.044
Flash Point 160.5±24.6 °C
Exact Mass 261.949066
PSA 37.30000
LogP 3.57
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.646
Name: 3-Iodo-2-methylbenzoic acid Material Safety Data Sheet
Synonym:
CAS: 133232-56-1
Section 1 - Chemical Product MSDS Name:3-Iodo-2-methylbenzoic acid Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
133232-56-1 3-Iodo-2-methylbenzoic acid unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 133232-56-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: gray-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 124 - 126 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H7IO2
Molecular Weight: 262.04

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen iodide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 133232-56-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Iodo-2-methylbenzoic acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 133232-56-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 133232-56-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 133232-56-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
HS Code 2916399090

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133232-56-1

Literature: Kung, Pei-Pei; Funk, Lee; Meng, Jerry; Collins, Michael; Zhou, Joe Zhongxiang; Catherine Johnson; Ekker, Anne; Wang, Jeff; Mehta, Pramod; Yin, Min-Jean; Rodgers, Caroline; Davies II, Jay F.; Bayman, Eileen; Smeal, Tod; Maegley, Karen A.; Gehring, Michael R. Bioorganic and Medicinal Chemistry Letters, 2008 , vol. 18, # 23 p. 6273 - 6278

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Literature: EP1642881 A1, ; Page/Page column 6 ;

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133232-56-1 structure

133232-56-1

Detail
Literature: EP1595862 A1, ; Page/Page column 11-12 ;

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133232-56-1 structure

133232-56-1

Literature: Tetrahedron Letters, , vol. 39, # 47 p. 8589 - 8592

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133232-56-1 structure

133232-56-1

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2940 - 2948

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133232-56-1 structure

133232-56-1

Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 2940 - 2948
HS Code 2916399090
Summary 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%