12039-83-7

12039-83-7 structure
12039-83-7 structure

Name bis(λ2-silanylidene)titanium
Synonyms Titanium silicide (TiSi2)
Titanium disilicide
MFCD00049564
TITANIUM SILICIDE,TiSi
EINECS 234-902-2
EINECS 234-904-3
Density 4,39 g/cm3
Boiling Point 1540ºC
Melting Point 1540ºC
Molecular Formula Si2Ti
Molecular Weight 104.03800
Exact Mass 103.90200

Section 1: Product Identification
Chemical Name:Titanium silicide (99+%-Ti)
CAS Registry Number:12039-83-7
Formula:TiSi2
EINECS Number:234-904-3
Chemical Family:metal silicide
Synonym:Titanium disilicide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound12039-83-7100%no datano data

Section 3: Hazards Identification
Emergency Overview:May be irritating to skin, eyes and mucous membranes.
Primary Routes of Exposure:Ingestion
Eye Contact:May cause mild to moderate irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Inhalation:Dust may be irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information is available on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide or dry powder
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus.
Hazardous Combustion andIf involved in a fire toxic oxidation or decomposition products may form.
Decomposion Products:
Unusual Fire or Explosion Hazards: May be fire or explosion hazard if in the form of a fine dust mixed with air.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Sweep up the solids and dispose of properly.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a sealed container. Keep away from heat.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:-325 mesh gray to black powder
Molecular Weight:112.03
Melting Point:1540°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:4.39
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:No hazardous polymerization.
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes F+
RIDADR UN3178
Packaging Group III
Hazard Class 4.1