Name | 4,4-dimethyl-1-phenylpyrazolidin-3-one |
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Synonyms |
4,4-Dimethyl-1-phenyl-3-pyrazolidinone
4,4-dimethyl-1-phenylpyrazolidin-3-one 4,4-Dimethyl-1-phenyl-3-pyrazolidone 1-Phenyl-4,4-dimethyl-3-pyrazolidinon 3-Pyrazolidinone,4,4-dimethyl-1-phenyl 3-Pyrazolidinone, 4,4-dimethyl-1-phenyl- 1-Phenyl-4,4-dimethyl-3-pyrazolidon 4,4-Dimethylphenidone 4,4-dimethyl-1-phenyl-pyrazolidin-3-one EINECS 220-181-1 Dimezone MFCD00044325 |
Density | 1.1±0.1 g/cm3 |
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Melting Point | 167-172 °C(lit.) |
Molecular Formula | C11H14N2O |
Molecular Weight | 190.242 |
Flash Point | 195 °C |
Exact Mass | 190.110611 |
PSA | 32.34000 |
LogP | 1.22 |
Index of Refraction | 1.537 |
Water Solubility | soluble |
Synonym:3-pyrazolidinone, 4,4-dimethyl-1-phenyl Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: Dust may cause mechanical irritation. No information reported. Skin: May cause skin irritation. No information reported. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Section 7 - HANDLING and STORAGE Handling: Wash hands before eating. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 2654-58-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: white to off-white to pink Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 167.00 - 169.00 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: soluble Specific Gravity/Density: Molecular Formula: C11H14N2O Molecular Weight: 190.24 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Strong oxidants. Incompatibilities with Other Materials: None reported. Hazardous Decomposition Products: No data available. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2654-58-2: UQ8710000 LD50/LC50: CAS# 2654-58-2: Oral, rat: LD50 = 30 mg/kg. Carcinogenicity: 3-pyrazolidinone, 4,4-dimethyl-1-phenyl- - Not listed by ACGIH, IARC, or NTP. Other: See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 2654-58-2: No information available. Canada CAS# 2654-58-2 is listed on Canada's DSL List. CAS# 2654-58-2 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2654-58-2 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
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Hazard Codes | T:Toxic; |
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Risk Phrases | R25;R36/37/38;R43 |
Safety Phrases | S26-S36/37-S45-S37/39-S28A-S24 |
RIDADR | UN 2811 6.1/PG 2 |
WGK Germany | 2 |
RTECS | UQ8710000 |
Packaging Group | II |
Hazard Class | 6.1 |
HS Code | 2933990090 |
~% 2654-58-2 |
Literature: Eastman Kodak Co. Patent: US2843598 , 1956 ; |
~% 2654-58-2 |
Literature: Eastman Kodak Co. Patent: US2772282 , 1953 ; |
Precursor 3 | |
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DownStream 0 |
HS Code | 2933990090 |
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Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |