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64485-88-7

64485-88-7 structure
64485-88-7 structure
  • Name: Ethyl 2-(2-aminothiazol-4-yl)-2-methoxyiminoacetate
  • Chemical Name: Ethyl 2-(2-aminothiazol-4-yl)-2-methoxyiminoacetate
  • CAS Number: 64485-88-7
  • Molecular Formula: C8H11N3O3S
  • Molecular Weight: 229.256
  • Create Date: 2018-09-06 14:51:23
  • Modify Date: 2024-01-02 14:46:58

Name Ethyl 2-(2-aminothiazol-4-yl)-2-methoxyiminoacetate
Synonyms MFCD00010588
ate
EINECS 264-912-2
emata
Ethyl-2-Methoxy-amino-2-(2-amino-4-thiazole-4-yl) acetate
Ethyl (2Z)-(2-amino-1,3-thiazol-4-yl)(methoxyimino)acetate
4-Thiazoleacetic acid, 2-amino-α-(methoxyimino)-, ethyl ester, (αE)-
4-Thiazoleacetic acid, 2-amino-α-(methoxyimino)-, ethyl ester, (αZ)-
Ethyl (2E)-(2-amino-1,3-thiazol-4-yl)(methoxyimino)acetate
Density 1.4±0.1 g/cm3
Boiling Point 363.4±34.0 °C at 760 mmHg
Melting Point 162-164 °C(lit.)
Molecular Formula C8H11N3O3S
Molecular Weight 229.256
Flash Point 173.6±25.7 °C
Exact Mass 229.052109
PSA 115.04000
LogP 1.00
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.606
Water Solubility may decompose
Name: Ethyl 2(2-Aminothiazole-4-yl)-2-Methoxyiminoacetate 98% Material Safety Data Sheet
Synonym: Ethyl 2-Amino-1-(Methoxyimino)-4-Thiazoleacetate
CAS: 64485-88-7
Section 1 - Chemical Product MSDS Name:Ethyl 2(2-Aminothiazole-4-yl)-2-Methoxyiminoacetate 98% Material Safety Data Sheet
Synonym:Ethyl 2-Amino-1-(Methoxyimino)-4-Thiazoleacetate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
64485-88-7 Ethyl, 2(2-Aminothiazole-4-yl)-2-Metho 98 264-912-2
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Moisture sensitive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 64485-88-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 159.00 - 160.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: may decompose
Specific Gravity/Density:
Molecular Formula: C8H11N3O3S
Molecular Weight: 229.23

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 64485-88-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl, 2(2-Aminothiazole-4-yl)-2-Methoxyiminoacetate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 64485-88-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 64485-88-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 64485-88-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
WGK Germany 3
HS Code 2934100090

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64485-88-7 structure

64485-88-7

Literature: US4278671 A1, ;

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64485-88-7 structure

64485-88-7

Literature: Tetrahedron, , vol. 34, p. 2233 - 2243
HS Code 2934100090
Summary 2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%