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473-29-0

473-29-0 structure
473-29-0 structure
  • Name: Dichloramine B
  • Chemical Name: N,N-dichlorobenzenesulfonamide
  • CAS Number: 473-29-0
  • Molecular Formula: C6H5Cl2NO2S
  • Molecular Weight: 226.08000
  • Create Date: 2018-07-23 18:46:05
  • Modify Date: 2024-01-20 12:40:39

Name N,N-dichlorobenzenesulfonamide
Synonyms N,N-dichlorobenzenesulphonamide
Benzenesulfonamide,N,N-dichloro
AC1Q6V9S
N,N-Dichlorobenzenesulfonamide
halogen h1
AC1L28XT
Benzenesulfonedichloramide
N,N-dichloro-benzenesulfonamide
N,N-dichloroamide of benzenesulfonic acid
N,N-Dichloroethylbenzenesulfonamide
N-dichlorobenzenesulfonamide
EINECS 207-461-9
Dichloramine B
Density 1.562g/cm3
Boiling Point 319.2ºC at 760mmHg
Melting Point 74ºC
Molecular Formula C6H5Cl2NO2S
Molecular Weight 226.08000
Flash Point 146.8ºC
Exact Mass 224.94200
PSA 45.76000
LogP 3.06570
Vapour Pressure 0.000344mmHg at 25°C
Index of Refraction 1.594
Dichloramine B
SAFETY DATA SHEET

Section1. IDENTIFICATION
Product name:Dichloramine B

Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS
Category 1
Oxidizing solids
HEALTH HAZARDS
Category 2
Skin corrosion/irritation
Serious eye damage/eye irritationCategory 2A
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Signal wordDanger
Hazard statementsMay cause fire or explosion; strong oxidizer
Causes skin irritation
Causes serious eye irritation
Precautionary statements:
Keep away from heat.
[Prevention]
Keep away from clothing and other combustible materials.
Take any precaution to avoid mixing with incompatible materials such as
combustibles.
Wash hands thoroughly after handling.
Wear protective gloves/eye protection/face protection.
Wear fire/flame resistant/retardant clothing.
[Response]IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of
water before removing clothes.
Take off contaminated clothing and wash before reuse.
In case of major fire and large quantities: Evacuate area. Fight fire remotely due to
the risk of explosion.
[Disposal]Dispose of contents/container through a waste management company authorized by
the local government.
Dichloramine B

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Components:Dichloramine B
Percent:>95.0%(T)
CAS Number:473-29-0
Synonyms:Benzenesulfonedichloramide
Chemical Formula:C6H5Cl2NO2S

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact:Rinse immediately contaminated clothing and skin with plenty of water before
removing clothes. Immediately call a POISON CENTER or doctor/physician.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Explosion risk in case of fire. Fight fire remotely due to the risk of explosion.
from the chemical:Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
spraying with water. Eliminate all ignition sources if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Keep people away from and upwind of spill/leak.
Personal precautions,
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.
Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
hazards:case of a fire. Use spark-proof tools and explosion-proof equipment. Since there is a
possibility of igniting behind when removal of a leakage thing is imperfect, it is careful
enough.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures:Handling is performed in a well ventilated place. Wear suitable protective equipment.
Be careful not to cause leakage, overflow, or dispersion. Steam should not be
generated unnecessarily. Keep away from heat/sparks/open flame/hot surfaces. -No
smoking. Take measures to prevent the build up of electrostatic charge. Use
explosion-proof equipment. Avoid shock and friction. Wash hands and face before
breaks and immediately after handling the product.
Use a local exhaust if dust or aerosol will be generated.
Avoid contact with skin, eyes and clothing.
Advice on safe handling:
Dichloramine B

Section7. HANDLING AND STORAGE
Don't leave used equipment or rag. This product may ignite if it is left stuck on
combustibles such as paper, rags, etc.
Conditions for safe storage, including any
incompatibilities
Storage conditions:Keep container tightly closed. Store in a cool and dark place.
Store under inert gas.
Be sure not to give the container unexpected impacts, such as falling down or falling
off.
Store away from combustibles.
Air-sensitive
Packaging material:Comply with laws.

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Hand protection:Protective gloves.
Safety glasses. A face-shield, if the situation requires.
Eye protection:
Skin and body protection: Fire/flame resistant/retardant protective clothing. Protective boots, if the situation
requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Solid
Form:Crystal- Powder
White - Slightly pale yellow green
Colour:
Odour:No data available
pH: No data available
Melting point/freezing point:74°C
No data available
Boiling point/range:
Flash point:No data available
Flammability or explosive
limits:
No data available
Lower:
Upper:No data available
Relative density:No data available
Solubility(ies):
No data available
[Water]
[Other solvents]
Methanol, Chloroform
Soluble:

Section10. STABILITY AND REACTIVITY
Chemical stability:Stable under proper conditions.
Possibility of hazardous May explosively decompose on heating, shock, friction, etc.
reactions:May cause fire or explosion on contact with reducing agents or mixing with
combustibles.
Conditions to avoid:Heat, Shock, Friction, Light
Incompatible materials: Oxidizing agents, Reducing agents, Strong acids, Combustibles, Organic substances
Hazardous decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), Sulfur oxides, Hydrogen
products:chloride

Section11. TOXICOLOGICAL INFORMATION
No data available
Acute Toxicity:
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Dichloramine B

Section11. TOXICOLOGICAL INFORMATION
Carcinogenicity:
No data available
IARC =
NTP =No data available
No data available
Reproductive toxicity:

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
Crustacea:No data available
Algae:No data available
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobility in soil
Log Pow:No data available
Soil adsorption (Koc):No data available
Henry's LawNo data available
constant(PaM3/mol):

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities and an expert of disposal. If it mixes with
inflammable solvents, it may catch fire. Observe all federal, state and local regulations when disposing of the
substance.

Section14. TRANSPORT INFORMATION
Hazards Class:5.1: Oxidizer.
UN-No:1479
Proper shipping name:Oxidizing solid, n.o.s.
Packing group:I

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi
Risk Phrases 8-36/37/38
Safety Phrases 17-26-36/37/39
RIDADR UN 1479
HS Code 2935009090

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Literature: Sanapo, Gabriel F.; Daoust, Benoit Tetrahedron Letters, 2008 , vol. 49, # 26 p. 4196 - 4199

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Literature: Derkach,N.Ya. et al. Journal of Organic Chemistry USSR (English Translation), 1979 , vol. 15, p. 1381 - 1384 Zhurnal Organicheskoi Khimii, 1979 , vol. 15, p. 1547 - 1551

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Literature: Derkach,N.Ya. et al. Zhurnal Organicheskoi Khimii, 1974 , vol. 10, # 9 p. 1873 - 1877,1884 - 1888

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Literature: Raju; Mohana; Yathirajan; Rangappa Indian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry, 2001 , vol. 40, # 6 p. 613 - 615

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Literature: Chattaway Journal of the Chemical Society, 1905 , vol. 87, p. 159

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473-29-0

Literature: Chattaway Journal of the Chemical Society, 1905 , vol. 87, p. 159
HS Code 2935009090
Summary 2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%