13862-78-7

13862-78-7 structure
13862-78-7 structure

Name ammonium tetrathiotungstate
Synonyms azane,bis(sulfanylidene)tungsten,sulfanide
Ammonium tetrathiotungstate
Disulfanyl(dithioxo)tungsten diammoniate
Tungsten, dimercaptodithioxo-, ammonium salt
MFCD00061410
Density 2.71 g/mL at 25 °C(lit.)
Molecular Formula H8N2S4W
Molecular Weight 348.177
Exact Mass 347.907928
PSA 148.26000
LogP 2.70520

Section 1: Product Identification
Chemical Name:Ammonium tetrathiotungstate (VI), 99% (99.9+%-W)
CAS Registry Number:13862-78-7
Formula:(NH4)2WS4
EINECS Number:none
Chemical Family:metal tungstate
Synonym:Ammonium thiotungstate (VI)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound13862-78-7100%1g/m3 (as W - soluble)no data

Section 3: Hazards Identification
Emergency Overview:Dust is irritating to eyes, skin and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, Inhalation of dust.
Eye Contact:Irritating to eyes. May cause redness and pain.
Skin Contact:Mildly irritating to skin. May cause itching and redness.
Inhalation:Inhalation of dust can lead to irritation of the respiratory tract, causing coughing and sore throat.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:None. Material is non-combustible.
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire, choking fumes of sulfur dioxide may form.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a tightly sealed container in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective gloves and clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow to orange xtl.
Molecular Weight:348.18
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:rotten egg odor
Solubility in Water:1g/15cc (turbid solution)

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:reaction with mineral acids
Incompatibility:Strong oxidizing agents and mineral acids
Decomposition Products:ammonia, nitrogen oxides, sulfur dioxide and tungsten compounds.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR UN 3335
WGK Germany 3

~82%

13862-78-7 structure

13862-78-7

Literature: Drew, Michael G. B.; Hobson, Richard J.; Mumba, Peter P. E. M.; Rice, David A.; Turp, Neil Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1987 , p. 1163 - 1168
Precursor  2

DownStream  1