16179-44-5

16179-44-5 structure
16179-44-5 structure
  • Name: 2-hydroxyethyl cyclohexanecarboxylate
  • Chemical Name: 2-hydroxyethyl cyclohexanecarboxylate
  • CAS Number: 16179-44-5
  • Molecular Formula: C9H16O3
  • Molecular Weight: 172.22200
  • Create Date: 2016-08-01 14:51:04
  • Modify Date: 2024-01-11 16:53:21

Name 2-hydroxyethyl cyclohexanecarboxylate
Synonyms Cyclohexancarbonsaeure-(1)-<2-hydroxy-ethylester>
EINECS 240-315-2
Cyclohexanecarboxylic acid,(2-hydroxyethyl) ester
Density 1.089g/cm3
Boiling Point 294.2ºC at 760mmHg
Molecular Formula C9H16O3
Molecular Weight 172.22200
Flash Point 124.9ºC
Exact Mass 172.11000
PSA 46.53000
LogP 1.10220
Vapour Pressure 0.000172mmHg at 25°C
Index of Refraction 1.478
Name: Ethyl Cis-2-Hydroxy-1-Cyclohexanecarboxylate (>98%) Material Safety Data Sheet
Synonym: Non
CAS: 16179-44-5
Section 1 - Chemical Product MSDS Name:Ethyl Cis-2-Hydroxy-1-Cyclohexanecarboxylate (>98%) Material Safety Data Sheet
Synonym:Non

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
16179-44-5 Ethyl Cis-2-Hydroxy-1-Cyclohexanecarbo >98 240-315-2
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16179-44-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 134.0 - 135.0 deg C @ 39.00mm
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0510g/cm3
Molecular Formula: C9H16O3
Molecular Weight: 172.22

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 16179-44-5: GU8580000 LD50/LC50:
CAS# 16179-44-5: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, skin: 550 mg/15D Mild; Oral, mouse: LD50 = >3200 uL/kg.
Carcinogenicity:
Ethyl Cis-2-Hydroxy-1-Cyclohexanecarboxylate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 16179-44-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16179-44-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16179-44-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
HS Code 2916209090

~99%

16179-44-5 structure

16179-44-5

Literature: Gonsalvi, Luca; Arends, Isabel W. C. E.; Moilanen, Pasi; Sheldon, Roger A. Advanced Synthesis and Catalysis, 2003 , vol. 345, # 12 p. 1321 - 1328

~80%

16179-44-5 structure

16179-44-5

Literature: Sharghi, Hashem; Sarvari, Mona Hosseini Tetrahedron, 2003 , vol. 59, # 20 p. 3627 - 3633
HS Code 2916209090
Summary 2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%