Name | 2,6-dichloro-4-isocyanatopyridine |
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Synonyms |
2,6-DICHLORO-4-PYRIDYL ISOCYANATE
4-(2,6-dichloro)pyridyl isocyanate 2,6-dichloro-4-isocyanato-pyridine 2,6-Dichloropyridin-4-yl isocyanate 2,5-DICHLOROAMYLAMINE HYDROCHLORIDE 2,6-dichloropyridin-4-isocyanate |
Density | 1.5g/cm3 |
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Boiling Point | 295.1ºC at 760mmHg |
Molecular Formula | C6H2Cl2N2O |
Molecular Weight | 188.99900 |
Flash Point | 132.3ºC |
Exact Mass | 187.95400 |
PSA | 42.32000 |
LogP | 2.35570 |
Vapour Pressure | 0.00156mmHg at 25°C |
Index of Refraction | 1.613 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 159178-03-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: colorless Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 105 - 108 deg C @8mmHg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C6H2Cl2N2O Molecular Weight: 189 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Oxidizing agents, bases, amines, alcohols. Hazardous Decomposition Products: Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 159178-03-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 2,6-Dichloro-4-pyridyl isocyanate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.* Hazard Class: 6.1 UN Number: 2811 Packing Group: II IMO Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing Group: II RID/ADR Shipping Name: TOXIC SOLID, ORGANIC, N.O.S. Hazard Class: 6.1 UN Number: 2811 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 159178-03-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 159178-03-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 159178-03-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xn:Harmful; |
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Risk Phrases | 23/24/25-34 |
Safety Phrases | 26-36/37/39 |
RIDADR | UN 2206 |
HS Code | 2933399090 |
~% 159178-03-7 |
Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 18, # 1 p. 309 - 312 |
~% 159178-03-7 |
Literature: US4308054 A1, ; |
~% 159178-03-7 |
Literature: Organic Letters, , vol. 10, # 19 p. 4383 - 4386 |
~% 159178-03-7 |
Literature: Arkivoc, , vol. 2011, # 6 p. 92 - 119 |
~% 159178-03-7 |
Literature: Arkivoc, , vol. 2011, # 6 p. 92 - 119 |
~% 159178-03-7 |
Literature: Arkivoc, , vol. 2011, # 6 p. 92 - 119 |
~% 159178-03-7 |
Literature: Arkivoc, , vol. 2011, # 6 p. 92 - 119 |
Precursor 8 | |
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DownStream 3 | |
HS Code | 2933399090 |
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Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |