13859-68-2

13859-68-2 structure
13859-68-2 structure
  • Name: azane,diiodonickel
  • Chemical Name: azane,diiodonickel
  • CAS Number: 13859-68-2
  • Molecular Formula: H18I2N6Ni
  • Molecular Weight: 414.68500
  • Create Date: 2018-08-15 23:15:04
  • Modify Date: 2024-01-02 11:49:17

Name azane,diiodonickel
Synonyms Nickel(2+),hexaammine-,diiodide,(OC-6-11)-(9CI)
Hexaamminenickel(II) iodide
Hexaamminenickel(2+) diiodide
MFCD00058808
Nickel(2+),hexaammine-,diiodide (8CI)
Hexaamminenickeldiiodide (6CI,7CI)
Hexaamminenickel iodide
Molecular Formula H18I2N6Ni
Molecular Weight 414.68500
Exact Mass 413.90400
PSA 19.44000

Section 1: Product Identification
Chemical Name:Hexaamminenickel (II) iodide,98%
CAS Registry Number:13859-68-2
Formula:[Ni(NH3)6]I2
EINECS Number:237-205-1
Chemical Family:metal-ammine complexes
Synonym:Nickel, hexammine (II) iodide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13859-68-2100%0.1mg/m3 (as Ni)1mg/m3 (as Ni)

Section 3: Hazards Identification
Ingestion of nickel salts may cause intestinal disorders, convulsions, and asphyxia. Irritating to skin, eyes and
Emergency Overview:
respiratory tract. May cause cancer.
Primary Routes of Exposure:Ingestion, inhalation of dust
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin. Prolonged contact with nickel salts may lead to dermatitis.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. May cause intestinal disorders, convulsions, asphyxia,
Acute Health Affects:
sensitization dermatitis, allergic asthma and pneumonitis.
Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis, and affect
Chronic Health Affects:
kidney, liver, and lung function. May cause cancer.
NTP:Yes
IARC:Yes
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow pwdr.
Molecular Weight:414.7
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:2.101
Odor:none
Solubility in Water:soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:nickel oxide, ammonia, and nickel iodide

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:Carcinogen (as Ni)
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound: See category code N495 for reporting.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes T: Toxic;
Risk Phrases 45-42/43
Safety Phrases 53-36/37/39-45