Name | 4-n-pentyloxybenzoyl chloride |
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Synonyms |
EINECS 253-230-0
4-pentoxybenzoyl chloride MFCD00041723 |
Density | 1.101g/cm3 |
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Boiling Point | 324.5ºC at 760mmHg |
Melting Point | 160ºC |
Molecular Formula | C12H15ClO2 |
Molecular Weight | 226.69900 |
Flash Point | 120.5ºC |
Exact Mass | 226.07600 |
PSA | 26.30000 |
LogP | 3.63460 |
Index of Refraction | 1.542-1.544 |
Synonym:None Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Moisture sensitive.Lachrymator (substance which increases the flow of tears). Potential Health Effects Eye: Lachrymator (substance which increases the flow of tears). Causes eye irritation and possible burns. Skin: Causes skin irritation and possible burns. Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. The toxicological properties of this substance have not been fully investigated. Inhalation: The toxicological properties of this substance have not been fully investigated. Causes respiratory tract irritation with possible burns. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub eyes or keep eyes closed. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Extinguishing Media: If water is the only media available, use in flooding amounts. DO NOT USE WATER! Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Use dry chemical, CO2 or dirt. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. Do not get water inside containers. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 36823-84-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: colorless Odor: chlorine-like pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 160 deg C @ 6.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 109 deg C (> 228.20 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: May decompose. Specific Gravity/Density: 1.087 Molecular Formula: C12H15ClO2 Molecular Weight: 226.70 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions. Conditions to Avoid: Incompatible materials, moisture, excess heat, strong oxidants. Incompatibilities with Other Materials: Moisture, alcohols, strong oxidizing agents, strong bases. Hazardous Decomposition Products: Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 36823-84-4 unlisted. LD50/LC50: Not available. Carcinogenicity: Benzoyl Chloride, 4-(Pentyloxy)- - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 28A After contact with skin, wash immediately with plenty of water. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 36823-84-4: No information available. Canada CAS# 36823-84-4 is listed on Canada's NDSL List. CAS# 36823-84-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 36823-84-4 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | C: Corrosive; |
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Risk Phrases | R34 |
Safety Phrases | 45-36/37/39-26 |
RIDADR | UN 3265 |
Packaging Group | II |
HS Code | 2918990090 |
~93% 36823-84-4 |
Literature: Maksimenko; Novikova; Kondrat'Eva; Kuz'Min; Ognichenko; Yarkova Russian Journal of Organic Chemistry, 2007 , vol. 43, # 12 p. 1773 - 1780 |
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Literature: Mundhe Journal of the Indian Chemical Society, 1999 , vol. 76, # 5 p. 246 - 249 |
~% 36823-84-4 |
Literature: Tinh; Pourrere; Destrade Molecular crystals and liquid crystals, 1980 , vol. 62, # 1-2 p. 125 - 139 |
~% 36823-84-4 |
Literature: Mundhe Journal of the Indian Chemical Society, 1999 , vol. 76, # 5 p. 246 - 249 |
~% 36823-84-4 |
Literature: Mundhe Journal of the Indian Chemical Society, 1999 , vol. 76, # 5 p. 246 - 249 |
~% 36823-84-4 |
Literature: Malthete, Jacques; Canceill, Josette; Gabard, Jacqueline; Jacques, Jean Tetrahedron, 1981 , vol. 37, # 16 p. 2815 - 2821 |
~% 36823-84-4 |
Literature: Mundhe Journal of the Indian Chemical Society, 1999 , vol. 76, # 5 p. 246 - 249 |
~% 36823-84-4 |
Literature: Eastman Kodak Co. Patent: US2423730 , 1944 ; |
~% 36823-84-4 |
Literature: Eastman Kodak Co. Patent: US2423730 , 1944 ; |
Precursor 9 | |
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DownStream 2 | |
HS Code | 2918990090 |
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Summary | 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |