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6485-55-8

6485-55-8 structure
6485-55-8 structure
  • Name: cis-2,6-Dimethylmorpholine
  • Chemical Name: cis-2,6-Dimethylmorpholine
  • CAS Number: 6485-55-8
  • Molecular Formula: C6H13NO
  • Molecular Weight: 115.174
  • Create Date: 2018-07-14 15:14:24
  • Modify Date: 2024-01-09 15:46:22

Name cis-2,6-Dimethylmorpholine
Synonyms (2R,6S)-2,6-Dimethylmorpholine
trans-2,6-dimethylmorpholine
MFCD00078428
(2S,6R)-2,6-dimethylmorpholine
MORPHOLINE, 2,6-DIMETHYL-, CIS-
cis 2,6-dimethylmorpholine
Morpholine, 2,6-dimethyl-, (2R,6S)-
dimethylamine hydrochloride
EINECS 229-353-0
2,6-cis-dimethylmorpholine
R,R-2,6-dimethylmorpholine
CIS-2,6-DIMETHYL MORPHOLINE
Density 0.9±0.1 g/cm3
Boiling Point 146.6±0.0 °C at 760 mmHg
Melting Point -85ºC
Molecular Formula C6H13NO
Molecular Weight 115.174
Flash Point 48.9±0.0 °C
Exact Mass 115.099716
PSA 21.26000
LogP -0.10
Vapour Pressure 4.6±0.2 mmHg at 25°C
Index of Refraction 1.406
Storage condition Flammables area
Name: cis-2 6-Dimethylmorpholine 97% Material Safety Data Sheet
Synonym:
CAS: 6485-55-8
Section 1 - Chemical Product MSDS Name:cis-2 6-Dimethylmorpholine 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6485-55-8 cis-2,6-Dimethylmorpholine 97% 229-353-0
Hazard Symbols: C
Risk Phrases: 10 21/22 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable. Harmful in contact with skin and if swallowed. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Cover with sand, dry lime or soda ash and place in a closed container for disposal. Remove all sources of ignition. Use a spark-proof tool. Isolate area and deny entry.

Section 7 - HANDLING and STORAGE
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Store below 35C.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6485-55-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear colorless
Odor: Not available.
pH: 11.8 (100 g/l (20C))
Vapor Pressure: 7mbar @20 deg C
Viscosity: 5.3 mPa.s @20 deg C
Boiling Point: 140 - 142 deg C @760mmHg
Freezing/Melting Point: -85 deg C
Autoignition Temperature: 280 deg C ( 536.00 deg F)
Flash Point: 41 deg C ( 105.80 deg F)
Explosion Limits, lower: 1.6 Vol %
Explosion Limits, upper: 12.9 Vol %
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 0.930
Molecular Formula: C6H13NO
Molecular Weight: 115.18

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6485-55-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
cis-2,6-Dimethylmorpholine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.*
Hazard Class: 8 (3)
UN Number: 2734
Packing Group: II
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2734
Packing Group: II
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S.
Hazard Class: 8 (3)
UN Number: 2734
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 21/22 Harmful in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6485-55-8: 1
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6485-55-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6485-55-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes C: Corrosive;
Risk Phrases R10;R21;R37/38;R41
Safety Phrases S26-S36/37/39
RIDADR UN 1993
RTECS QE1750000
Packaging Group III
Hazard Class 3
HS Code 2934999090
HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%