71648-20-9

71648-20-9 structure
71648-20-9 structure
  • Name: 1,5,5-trichloro-7-oxabicyclo[4.1.0]heptane
  • Chemical Name: 2,2,6-trichloro-7-oxabicyclo[4.1.0]heptane
  • CAS Number: 71648-20-9
  • Molecular Formula: C6H7Cl3O
  • Molecular Weight: 201.47800
  • Create Date: 2017-10-09 12:44:33
  • Modify Date: 2024-04-03 18:14:01

Name 2,2,6-trichloro-7-oxabicyclo[4.1.0]heptane
Synonyms 1,3,3-trichloro-7-oxabicyclo<4.1.0>heptane
EINECS 275-748-6
Density 1.51g/cm3
Boiling Point 270.8ºC at 760 mmHg
Molecular Formula C6H7Cl3O
Molecular Weight 201.47800
Flash Point 115.1ºC
Exact Mass 199.95600
PSA 12.53000
LogP 2.67810
Index of Refraction 1.543
Version 1.0
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product Name2,6,6-TRICHLORO-1,2-EPOXYCYCLO - 250 MG
HEXANE

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Causes burns. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.

3 - Composition/Information on Ingredients

Product NameCAS #EC noAnnex I
Index Number
2,6,6-TRICHLORO-1,2-EPOXYCYCLOHEXA 71648-20-9 275-748-6 None
NE
FormulaC6H7Cl3O

4 - First Aid Measures

AFTER INHALATION
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
AFTER SKIN CONTACT
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
AFTER EYE CONTACT
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
AFTER INGESTION
If swallowed, wash out mouth with water provided person is
conscious. Call a physician. Do not induce vomiting.

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5 - Fire Fighting Measures

EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
SPECIAL RISKS
Specific Hazard(s): Emits toxic fumes under fire conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
Wear self-contained breathing apparatus and protective clothing
to prevent contact with skin and eyes.

6 - Accidental Release Measures

PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.
ADDITIONAL INFORMATION
Avoid contact with eyes, skin, and clothing.

7 - Handling and Storage

HANDLING
Directions for Safe Handling: Do not breathe vapor. Do not get
in eyes, on skin, on clothing. Avoid prolonged or repeated
exposure.
STORAGE
Conditions of Storage: Keep tightly closed.

8 - Exposure Controls / Personal Protection

ENGINEERING CONTROLS
Safety shower and eye bath. Use only in a chemical fume hood.
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes. Wash thoroughly after handling.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US)
or CEN (EU). Where risk assessment shows air-purifying respirators
are appropriate use a full-face respirator with multi-purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as
a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator.
Hand Protection: Compatible chemical-resistant gloves.
Eye Protection: Chemical safety goggles.
Special Protective Measures: Faceshield (8-inch minimum).
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9 - Physical and Chemical Properties

AppearancePhysical State: Liquid
PropertyValueAt Temperature or Pressure
pH N/A
BP/BP RangeN/A
MP/MP RangeN/A
Flash PointN/A
FlammabilityN/A
Autoignition TempN/A
Oxidizing Properties N/A
Explosive Properties N/A
Explosion LimitsN/A
Vapor PressureN/A
ViscosityN/A
Vapor DensityN/A
Saturated Vapor Conc. N/A
Evaporation RateN/A
Bulk DensityN/A
Decomposition Temp.N/A
Solvent ContentN/A
Water ContentN/A
Surface TensionN/A
ConductivityN/A
Miscellaneous DataN/A
SolubilityN/A

10 - Stability and Reactivity

STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Hydrogen chloride gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur

11 - Toxicological Information

SENSITIZATION
Sensitization: Possible sensitizer.
Skin: Prolonged or repeated exposure may cause allergic
reactions in certain sensitive individuals. The preceding data,
or interpretation of data, was determined using Quantitative
Structure Activity Relationship (QSAR) modeling.
SIGNS AND SYMPTOMS OF EXPOSURE
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. Material is extremely destructive to tissue of the
mucous membranes and upper respiratory tract, eyes, and skin.
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
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ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns.
Inhalation: May be harmful if inhaled. Material is extremely
destructive to the tissue of the mucous membranes and upper
respiratory tract.
Ingestion: May be harmful if swallowed.

12 - Ecological Information

No data available.

13 - Disposal Considerations

SUBSTANCE DISPOSAL
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.

14 - Transport Information

RID/ADR
UN#: 1760
Class: 8
PG: III
Proper Shipping Name: Corrosive liquid, n.o.s.
IMDG
UN#: 1760
Class: 8
PG: III
Proper Shipping Name: Corrosive liquid, n.o.s.
Marine Pollutant: No
Severe Marine Pollutant: No
Technical Name: Required
IATA
UN#: 1760
Class: 8
PG: III
Proper Shipping Name: Corrosive liquid, n.o.s.
Inhalation Packing Group I: No
Technical Name: Required

15 - Regulatory Information

CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
INDICATION OF DANGER: C-N
Corrosive. Dangerous for the environment.
R-PHRASES: 34-51/53
Causes burns. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S-PHRASES: 26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice. Wear suitable protective
clothing, gloves, and eye/face protection. In case of accident
or if you feel unwell, seek medical advice immediately (show
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the label where possible).

16 - Other Information

WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2010 Co. License granted to make
unlimitedpaper copies for internal use only.
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
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71648-20-9 structure

71648-20-9

Literature: Duhamel, Pierre; Leblond, Bertrand; Poirier, Jean-Marie Journal of the Chemical Society, Chemical Communications, 1993 , # 5 p. 476 - 477

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71648-20-9 structure

71648-20-9

Literature: Duhamel, Pierre; Leblond, Bertrand; Bidois-Sery, Laure; Poirier, Jean-Marie Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 16 p. 2265 - 2272