Name | tris(cyclopentadienyl)lanthanum |
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Synonyms |
EINECS 215-049-5
MFCD00045467 (C5H5)3La Lanthanum (III) tris(cyclopentadienyl) Tris(cyclopentadienyl)lanthanum ( La) (REO) tris(eta5-cyclopenta-2,4-dien-1-yl)lanthanum Tris(cyclopentadienyl)lanthanum(III) (REO) |
Boiling Point | 41.5ºC at 760 mmHg |
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Melting Point | 275ºC |
Molecular Formula | C15H15La |
Molecular Weight | 334.18500 |
Flash Point | >230 °F |
Exact Mass | 334.02400 |
LogP | 3.06450 |
Vapour Pressure | 418mmHg at 25°C |
Section 1: Product Identification Chemical Name:Tris(cyclopentadienyl)lanthanum (99.9%-La) (REO) CAS Registry Number:1272-23-7 Formula:(C5H5)3La EINECS Number:215-049-5 Chemical Family:metallocene Synonym:tris(eta5-2,4-cyclopentadien-1-yl)lanthanum, lanthanum dicyclopentadienide
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound1272-23-7100%no datano data Section 3: Hazards Identification Emergency Overview:May be irritating to skin, eyes, and mucous membranes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation Eye Contact:May cause slight to mild irritation of the eyes. Skin Contact:May cause slight to mild irritation of the skin. Inhalation:May cause irritation to the nose, mucous membranes and respiratory tract. Ingestion:No information available on the effects of ingestion. Acute Health Affects:May be irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide or dry powder If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Flammable solid. Dust may form explosive mixtures with air. SECTION 6: Accidental Release Measures Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and Spill and Leak Procedures: swept up. SECTION 7: Handling and Storage Store and handle the material under an inert atmosphere of dry nitrogen or argon. Keep away from heat, air Handling and Storage: and moisture. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white to off-white xtl. Molecular Weight:334.19 Melting Point:295° dec. Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:Air and moisture. Keep away from ignition sources. Incompatibility:halogens and oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, lanthanum oxide and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data available Mutagenic Effects:no data available Tetratogenic Effects:no data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
Symbol |
GHS02 |
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Signal Word | Danger |
Hazard Statements | H228-H261 |
Supplemental HS | Reacts violently with water. |
Precautionary Statements | P210-P231 + P232-P422 |
Personal Protective Equipment | Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
Hazard Codes | F: Flammable; |
Risk Phrases | R11 |
Safety Phrases | 43-7/8 |
RIDADR | UN 3395 4 |
Packaging Group | III |
Hazard Class | 4.1 |
~86% 1272-23-7 |
Literature: Eggers, Stefan H.; Kopf, Juergen; Fischer, R. Dieter Organometallics, 1986 , vol. 5, p. 383 - 385 |
Precursor 1 | |
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DownStream 0 |