62269-44-7
- Name: Methyl 3-((trimethylsilyl)oxy)-2-butenoate
- Chemical Name: 3-(trimethylsilyloxy)crotonic acid methyl ester
- CAS Number: 62269-44-7
- Molecular Formula: C8H16O3Si
- Molecular Weight: 188.296
- Catalog: Chemical reagent Silane reagent
- Create Date: 2019-02-02 18:19:55
- Modify Date: 2024-01-09 12:22:08
| Name | 3-(trimethylsilyloxy)crotonic acid methyl ester |
|---|---|
| Synonyms |
2-Butenoic acid, 3-[(trimethylsilyl)oxy]-, methyl ester, (2E)-
3-TRIMETHYLSILOXY-2-BUTENOIC ACID METHYL ESTER Methyl (2Z)-3-[(trimethylsilyl)oxy]but-2-enoate methyl 3-trimethylsilyloxy-2-butenoate methyl 3-trimethylsiloxybut-2-enoate MFCD00008457 Methyl (2Z)-3-[(trimethylsilyl)oxy]-2-butenoate Methyl 3-((trimethylsilyl)oxy)-2-butenoate METHYL ACETOACETATE ENOL TRIMETHYLSILYL ETHER 2-Butenoic acid, 3-[(trimethylsilyl)oxy]-, methyl ester, (2Z)- Methyl (2E)-3-[(trimethylsilyl)oxy]-2-butenoate METHYL 3-TRIMETHYLSILOXY-2-BUTENOATE EINECS 263-483-9 |
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 178.6±23.0 °C at 760 mmHg |
| Molecular Formula | C8H16O3Si |
| Molecular Weight | 188.296 |
| Flash Point | 63.9±0.0 °C |
| Exact Mass | 188.086868 |
| PSA | 35.53000 |
| LogP | 2.25 |
| Vapour Pressure | 1.0±0.3 mmHg at 25°C |
| Index of Refraction | 1.427 |
| Storage condition | 2-8°C |
| Hazard Codes | Xi |
|---|---|
| Risk Phrases | 36/37/38-10 |
| Safety Phrases | 26-36/37/39-24/25-23 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| Packaging Group | III |
| Hazard Class | 3.2 |
| HS Code | 2931900090 |
|
~86%
62269-44-7 |
| Literature: Kimura, Masanari; Ezoe, Akihiro; Mori, Masahiko; Iwata, Keisuke; Tamaru, Yoshinao Journal of the American Chemical Society, 2006 , vol. 128, # 26 p. 8559 - 8568 |
|
~83%
62269-44-7 |
| Literature: Organix, Inc.; President and Fellows of Harvard College Patent: US5770180 A1, 1998 ; US 5770180 A |
|
~88%
62269-44-7 |
| Literature: Aizpurua, Jesus Mari; Palomo, Claudio Synthesis, 1982 , # 4 p. 280 - 281 |
|
~%
62269-44-7 |
| Literature: Synthesis, , p. 722 - 724 |
|
~%
62269-44-7 |
| Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 40, # 1 p. 97 - 104,88 - 93 |
|
~%
62269-44-7 |
| Literature: Liebigs Annalen der Chemie, , # 7 p. 1237 - 1248 |
|
~%
62269-44-7 |
| Literature: Organic Mass Spectrometry, , vol. 22, p. 486 - 492 |
|
~%
62269-44-7 |
| Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 40, # 1 p. 97 - 104,88 - 93 |
|
~%
62269-44-7 |
| Literature: Zeitschrift fuer Chemie (Stuttgart, Germany), , vol. 28, # 11 p. 409 - 410 |
| Precursor 8 | |
|---|---|
| DownStream 4 | |
![[2-(Trimethylsiloxy)ethyl]benzene structure](https://image.chemsrc.com/caspic/393/14629-58-4.png)
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |