16743-33-2

16743-33-2 structure
16743-33-2 structure
  • Name: ZINC HEXAFLUOROACETYLACETONATE DIHYDRATE
  • Chemical Name: zinc,1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,dihydrate
  • CAS Number: 16743-33-2
  • Molecular Formula: C10H6F12O6Zn
  • Molecular Weight: 515.51200
  • Create Date: 2018-04-29 08:00:00
  • Modify Date: 2024-01-07 11:04:22

Name zinc,1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,dihydrate
Synonyms MFCD00150577
Hexafluoroacetylacetone zinc derivative
zinc(II) bis(hexafluoroacetylacetonate)dihydrate
Boiling Point 114.1ºC at 760mmHg
Melting Point 157-158ºC
Molecular Formula C10H6F12O6Zn
Molecular Weight 515.51200
Flash Point 22.8ºC
Exact Mass 513.92600
PSA 71.06000
LogP 3.95870
Vapour Pressure 10.3mmHg at 25°C

Section 1: Product Identification
Chemical Name:Zinc hexafluoroacetylacetonate hydrate, min. 98%
CAS Registry Number:16743-33-2
Formula:Zn(CF3COCHCOCF3)2.2H2O
EINECS Number:None
Chemical Family:metal fluorobeta-diketonate complexes
Synonym:Zinc hexafluoro 2,4-pentanedionate

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound16743-33-2100%2.5mg/m3 (as F)2.5mg/m3 (as F)

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. Inhalation of high levels may produce symptoms known as metal
Emergency Overview:
fume fever or zinc shakes. These include chills, fever, nausea, and vomiting.
Primary Routes of Exposure:Ingestion, Inhalation of dust.
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Irritating to the nose, mucous membranes and respiratory tract. Inhalation may produce symptoms known as
Inhalation:
metal fume fever and zinc shakes.
Ingestion:Zinc salts have a harsh metallic taste.
Inhalation of dust may cause chills, muscle ache, nausea, fever, dry throat, cough; headache; blurred vision;
Acute Health Affects:
low back pain; vomiting; dyspnea (breathing difficulty), rales, and decreased pulmonary function
Prolonged or repeated exposure may cause breathing difficulty and decreased pulmonary function. In animal
Chronic Health Affects:
studies mutagenic and reproductive effects were observed after prolonged exposures to zinc oxide dust.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white pwdr.
Molecular Weight:479.47 (515.50)
Melting Point:157-158°C
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:Oxidizing agents
Decomposition Products:Fluorinated organics, carbon dioxide, carbon monoxide, organic fumes, and zinc oxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:Very toxic to aquatic organisms.

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound: See category N982 for reporting.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
RIDADR UN 3261