Name | methyl 3-(2-hydroxyphenyl)propanoate |
---|---|
Synonyms |
3-(2-hydroxyphenyl)propanoic acid methyl ester
methyl 3-(2-hydroxyphenyl)propionate methyl 2-(2-hydroxyphenyl)propionate o-hydrocoumaric acid methyl ester 3-(2-hydroxyphenyl)-propionic acid methyl ester MFCD00067757 2-hydroxybenzenepropanoic acid methyl ester |
Density | 1.146g/cm3 |
---|---|
Boiling Point | 280.2ºC at 760 mmHg |
Melting Point | 40ºC |
Molecular Formula | C10H12O3 |
Molecular Weight | 180.20000 |
Flash Point | 116.6ºC |
Exact Mass | 180.07900 |
PSA | 46.53000 |
LogP | 1.49780 |
Vapour Pressure | 0.00225mmHg at 25°C |
Index of Refraction | 1.532 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 20349-89-7: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 40 - 42 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C10H12O3 Molecular Weight: 180.2 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 20349-89-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Methyl 3-(2-hydroxyphenyl)propanoate - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 20349-89-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 20349-89-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 20349-89-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi:Irritant; |
---|---|
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S37/39 |
HS Code | 2918290000 |
~96% 20349-89-7 |
Literature: Williams, John D.; Khan, Atiyya R.; Cardinale, Steven C.; Butler, Michelle M.; Bowlin, Terry L.; Peet, Norton P. Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 1 p. 419 - 434 |
~85% 20349-89-7 |
Literature: Sugimoto, Hiromichi; Nakamura, Satoshi; Ohwada, Tomohiko Advanced Synthesis and Catalysis, 2007 , vol. 349, # 4-5 p. 669 - 679 |
~10% 20349-89-7 |
Literature: Barton, Patrick; Laws, Andrew P.; Page, Michael I. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1994 , # 9 p. 2021 - 2030 |
~% 20349-89-7 |
Literature: Advanced Synthesis and Catalysis, , vol. 349, # 4-5 p. 669 - 679 |
~% 20349-89-7 |
Literature: Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 407 - 410 |
~% 20349-89-7 |
Literature: DE562827 , ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 19, p. 655 |
~% 20349-89-7 |
Literature: Advanced Synthesis and Catalysis, , vol. 349, # 4-5 p. 669 - 679 |
~% 20349-89-7 |
Literature: Advanced Synthesis and Catalysis, , vol. 349, # 4-5 p. 669 - 679 |
~% 20349-89-7 |
Literature: Bioorganic and Medicinal Chemistry, , vol. 22, # 1 p. 419 - 434 |
Precursor 8 | |
---|---|
DownStream 3 | |
HS Code | 2918290000 |
---|---|
Summary | HS: 2918290000 other carboxylic acids with phenol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) VAT:17.0% MFN tariff:6.5% General tariff:30.0% |