13749-38-7

13749-38-7 structure
13749-38-7 structure

Name 1,2-Dibromo-1,1,2-trichloroethane
Synonyms 1,2-dibromo-1,1,2-trichloroethane
MFCD00018841
Density 1.701 g/mL at 25ºC(lit.)
Boiling Point 94-95ºC10 mm Hg(lit.)
Molecular Formula C2HBr2Cl3
Molecular Weight 291.19600
Flash Point >230 °F
Exact Mass 287.75100
LogP 3.47250
Vapour Pressure 0.417mmHg at 25°C
Index of Refraction n20/D 1.569(lit.)
Name: 1 2-Dibromo-1 1 2-trichloroethane 97% Material Safety Data Sheet
Synonym:
CAS: 13749-38-7
Section 1 - Chemical Product MSDS Name:1 2-Dibromo-1 1 2-trichloroethane 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13749-38-7 1,2-Dibromo-1,1,2-trichloroethane 97% 237-330-1
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
High vapor concentrations may cause drowsiness. May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Appearance: colourless
Odor: mild ether-like odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 200 deg C (> 392.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C2HBr2Cl3
Molecular Weight: 291.174

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, excess heat, temperatures above 200C.
Incompatibilities with Other Materials:
Metals, oxidizing agents, lithium, titanium, manganese.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, hydrogen bromide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 13749-38-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,2-Dibromo-1,1,2-trichloroethane - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 13749-38-7: No information available.
United Kingdom Occupational Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13749-38-7 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 13749-38-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
WGK Germany 3
HS Code 2903799090

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13749-38-7 structure

13749-38-7

Literature: Beit-Yannai, Michal; Rappoport, Zvi; Shainyan, Bagrat A.; Danilevich, Yuri S. Journal of Organic Chemistry, 1997 , vol. 62, # 23 p. 8049 - 8057

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13749-38-7 structure

13749-38-7

Literature: Drozdova, T. I.; Mirskova, A. N.; Levkovskaya, G. G.; Kalikhman, I. D.; Voronkov, M. G. Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 6 p. 1116 - 1119 Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 6 p. 1240 - 1243

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13749-38-7 structure

13749-38-7

Detail
Literature: Drozdova, T. I.; Mirskova, A. N.; Levkovkaya, G. G. Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 5.1 p. 862 - 865 Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 5 p. 1002 - 1005
HS Code 2903799090
Summary 2903799090 halogenated derivatives of acyclic hydrocarbons containing two or more different halogens。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%