Name | 1,2-Dibromo-1,1,2-trichloroethane |
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Synonyms |
1,2-dibromo-1,1,2-trichloroethane
MFCD00018841 |
Density | 1.701 g/mL at 25ºC(lit.) |
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Boiling Point | 94-95ºC10 mm Hg(lit.) |
Molecular Formula | C2HBr2Cl3 |
Molecular Weight | 291.19600 |
Flash Point | >230 °F |
Exact Mass | 287.75100 |
LogP | 3.47250 |
Vapour Pressure | 0.417mmHg at 25°C |
Index of Refraction | n20/D 1.569(lit.) |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: High vapor concentrations may cause drowsiness. May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Appearance: colourless Odor: mild ether-like odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 200 deg C (> 392.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C2HBr2Cl3 Molecular Weight: 291.174 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable. Conditions to Avoid: Incompatible materials, excess heat, temperatures above 200C. Incompatibilities with Other Materials: Metals, oxidizing agents, lithium, titanium, manganese. Hazardous Decomposition Products: Hydrogen chloride, phosgene, hydrogen bromide. Hazardous Polymerization: Will not occur. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 13749-38-7 unlisted. LD50/LC50: Not available. Carcinogenicity: 1,2-Dibromo-1,1,2-trichloroethane - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. See actual entry in RTECS for complete information. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 13749-38-7: No information available. United Kingdom Occupational Exposure Limits Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 13749-38-7 is not listed on Canada's Ingredient Disclosure List. Exposure Limits US FEDERAL TSCA CAS# 13749-38-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi: Irritant; |
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Risk Phrases | R36/37/38 |
Safety Phrases | 26-36 |
WGK Germany | 3 |
HS Code | 2903799090 |
~74% 13749-38-7 |
Literature: Beit-Yannai, Michal; Rappoport, Zvi; Shainyan, Bagrat A.; Danilevich, Yuri S. Journal of Organic Chemistry, 1997 , vol. 62, # 23 p. 8049 - 8057 |
~0% 13749-38-7 |
Literature: Drozdova, T. I.; Mirskova, A. N.; Levkovskaya, G. G.; Kalikhman, I. D.; Voronkov, M. G. Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 6 p. 1116 - 1119 Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 6 p. 1240 - 1243 |
~0% 13749-38-7
Detail
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Literature: Drozdova, T. I.; Mirskova, A. N.; Levkovkaya, G. G. Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 5.1 p. 862 - 865 Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 5 p. 1002 - 1005 |
Precursor 3 | |
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DownStream 5 | |
HS Code | 2903799090 |
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Summary | 2903799090 halogenated derivatives of acyclic hydrocarbons containing two or more different halogens。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |