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579-49-7

579-49-7 structure
579-49-7 structure
  • Name: 4-fluorophenyl 2-thienyl ketone
  • Chemical Name: (4-fluorophenyl)-thiophen-2-ylmethanone
  • CAS Number: 579-49-7
  • Molecular Formula: C11H7FOS
  • Molecular Weight: 206.23600
  • Create Date: 2018-06-24 15:12:09
  • Modify Date: 2024-01-05 10:25:57

Name (4-fluorophenyl)-thiophen-2-ylmethanone
Synonyms MFCD00044554
(4-fluorophenyl)-(thien-2-yl)ketone
(4-fluorophenyl)-(thiophen-2-yl)methanone
2-(4-fluorobenzoyl)-thiophene
(4-fluorophenyl)(2-thienyl)methanone
p-fluorophenyl thien-2-yl ketone
4-Fluorophenyl 2-thienyl ketone
EINECS 209-442-0
Density 1.279g/cm3
Boiling Point 314.7ºC at 760mmHg
Melting Point 94-99 °C
Molecular Formula C11H7FOS
Molecular Weight 206.23600
Flash Point 144.1ºC
Exact Mass 206.02000
PSA 45.31000
LogP 3.11820
Index of Refraction 1.59
Name: (4-Fluorophenyl)-(2-thienyl) ketone 97% Material Safety Data Sheet
Synonym: None
CAS: 579-49-7
Section 1 - Chemical Product MSDS Name:(4-Fluorophenyl)-(2-thienyl) ketone 97% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
579-49-7 (4-Fluorophenyl)-(2-thienyl) ketone 97 209-442-0
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 579-49-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: beige to brown
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 93.00 - 97.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: C11H7FOS
Molecular Weight: 206.23

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 579-49-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(4-Fluorophenyl)-(2-thienyl) ketone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 579-49-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 579-49-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 579-49-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases S37/39-S26
HS Code 2934999090

~89%

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Literature: Zhao, Weili; Carreira, Erick M. Chemistry - A European Journal, 2007 , vol. 13, # 9 p. 2671 - 2688

~79%

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579-49-7

Literature: Rao, Maddali L.N.; Venkatesh, Varadhachari; Banerjee, Debasis Tetrahedron, 2007 , vol. 63, # 52 p. 12917 - 12926

~%

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579-49-7

Literature: Advanced Synthesis and Catalysis, , vol. 346, # 13-15 p. 1836 - 1843

~74%

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579-49-7

Literature: Dunst, Cora; Knochel, Paul Synlett, 2011 , # 14 art. no. S03411ST, p. 2064 - 2068

~88%

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579-49-7

Literature: Zhou, Qing; Wei, Shaohua; Han, Wei Journal of Organic Chemistry, 2014 , vol. 79, # 3 p. 1454 - 1460

~71%

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579-49-7

Literature: Akhbar, Ahmed R.; Chudasama, Vijay; Fitzmaurice, Richard J.; Powell, Lyn; Caddick, Stephen Chemical Communications, 2014 , vol. 50, # 6 p. 743 - 746

~10%

579-49-7 structure

579-49-7

Literature: Keumi, Takashi; Yoshimura, Kiichiro; Shimada, Masakazu; Kitajima, Hidehiko Bulletin of the Chemical Society of Japan, 1988 , vol. 61, p. 455 - 460

~%

579-49-7 structure

579-49-7

Literature: Chemical Communications, , vol. 50, # 6 p. 743 - 746
HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%