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109-76-2

109-76-2 structure
109-76-2 structure

Name trimethylenediamine
Synonyms EINECS 203-702-7
1,3-Diaminopropane
1,3-BIAMINOPROPANE
RARECHEM AL BW 0043
FENTAMINE PDA
1,3-Diamino-n-propane
UNII-CB3ISL56KG
α,ω-propanediamine
Dap
MFCD00008228
1,3-Propylene diamine
1,3-diamino propane
TRIMETHYLENEDIAMINE
propane-1,3-diamine
1,3-Propanediamine
13DAP
3-Aminopropylamine
1,3-diamino-propane
1,3-propylenediamine
1,3 Diaminopropan
Density 0.9±0.1 g/cm3
Boiling Point 135.5±8.0 °C at 760 mmHg
Melting Point -12 °C
Molecular Formula C3H10N2
Molecular Weight 74.125
Flash Point 48.9±0.0 °C
Exact Mass 74.084396
PSA 52.04000
LogP -1.42
Vapour Pressure 7.7±0.2 mmHg at 25°C
Index of Refraction 1.451
Stability Stable. Hygroscopic. Flammable - readily forms explosive mixtures with air. Incompatible with acid anhydrides, acid chlorides, acids, strong oxidizing agents.
Water Solubility SOLUBLE

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TX6825000
CHEMICAL NAME :
1,3-Propanediamine
CAS REGISTRY NUMBER :
109-76-2
BEILSTEIN REFERENCE NO. :
0605277
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C3-H10-N2
MOLECULAR WEIGHT :
74.15
WISWESSER LINE NOTATION :
Z3Z

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 1/28/1963
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 1/28/1963 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
350 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
296 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKKZAJ Yakugaku Zasshi. Journal of Pharmacy. (Nippon Yakugakkai, 2-12-15 Shibuya, Shibuya-ku, Tokyo 150, Japan) No.1- 1881- Volume(issue)/page/year: 97,1117,1977
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
200 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
264 mg/kg
SEX/DURATION :
female 12 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Embryo or Fetus - other effects to embryo Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
TJADAB Teratology, The International Journal of Abnormal Development. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.1- 1968- Volume(issue)/page/year: 28,237,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0123 No. of Facilities: 61 (estimated) No. of Industries: 3 No. of Occupations: 5 No. of Employees: 2916 (estimated) No. of Female Employees: 1961 (estimated)
Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger
Hazard Statements H226-H302-H310-H314
Precautionary Statements P280-P302 + P350-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R10;R22;R24;R35
Safety Phrases S26-S36/37/39-S45-S25-S16
RIDADR UN 2922 8/PG 2
WGK Germany 2
RTECS TX6825000
Packaging Group III
Hazard Class 3
HS Code 29212900
HS Code 2921290000
Summary 2921290000 other acyclic polyamines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%