Name | Tetrakis-(2-hydroxyethyl)ammonium bromide |
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Synonyms |
tetraethanolammonium bromide
TETRAKIS(2-HYDROXYETHYL)AMMONIUM BROMIDE MFCD00041988 EINECS 224-362-6 |
Melting Point | 191ºC |
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Molecular Formula | C8H20BrNO4 |
Molecular Weight | 274.15300 |
Exact Mass | 273.05800 |
PSA | 80.92000 |
Synonym:Ethanaminium,2-Hydroxy-N,N,N-Tris(2-Hydroxyethyl)-, Bromide Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing Media: Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels. Exposure Limits CAS# 4328-04-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystalline powder Color: almost white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 191 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C8H20BrNO4 Molecular Weight: 274.15 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, excess heat, strong oxidants. Incompatibilities with Other Materials: Oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 4328-04-5 unlisted. LD50/LC50: Not available. Carcinogenicity: Tetrakis(2-Hydroxyethyl)Ammonium Bromide - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 4328-04-5: No information available. Canada CAS# 4328-04-5 is listed on Canada's NDSL List. CAS# 4328-04-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 4328-04-5 is listed on the TSCA inventory. SECTION 16 - ADDITIONAL INFORMATION N/A |
Safety Phrases | 24/25 |
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HS Code | 2923900090 |
~% 4328-04-5 |
Literature: JORDAN, Roy, Arlington Patent: WO2008/155520 A2, 2008 ; Location in patent: Page/Page column 12 ; |
~% 4328-04-5 |
Literature: I.G.Farbenind. Patent: US2173069 , 1937 ; Full Text Show Details I.G.Farbenind. Patent: US2137314 , 1936 ; Full Text Show Details I.G.Farbenind. Patent: FR806616 ; Full Text Show Details I.G.Farbenind. Patent: DE719817 , 1935 ; DRP/DRBP Org.Chem. Full Text Show Details Prod.Amines Soc.An. Patent: DE655882 , 1931 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 22, p. 723 Full Text Show Details I.G.Farbenind. Patent: DE681523 , 1934 ; |
~% 4328-04-5 |
Literature: Prelog; Blazek Collection of Czechoslovak Chemical Communications, 1934 , vol. 6, p. 484 |
Precursor 4 | |
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DownStream 0 |
HS Code | 2923900090 |
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Summary | 2923900090 other quaternary ammonium salts and hydroxides。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0% |